Fu, Xuegang; Wang, Yue; Liu, Liu; Li, Caifeng; Huang, Lin; Huang, Jianhui published the artcile< KOtBu/O2 Mediated Dehydrogenation of N-Heterocycles, Alcohols>, SDS of cas: 403-41-8, the main research area is heterocyclic compound preparation green chem; tetrahydroheterocyclic compound dehydrogenation; ketone preparation; alc dehydrogenation.
A convenient dehydrogenation of a number of N,O-containing heterocycles e.g., 1,2,3,4-tetrahydroquinoline and carbocycles RCH(OH)R1 (R = Ph, 3,4-dimethoxyphenyl, naphthalen-2-yl, pyridin-2-yl, etc.; R1 = Me, OH, t-Bu, Ph, Cy) and 1,2,3,4-tetrahydronaphthalen-1-ol with readily available inorganic base (KOtBu) and oxygen is reported. The oxidation process is proved to be an SRN1 pathway followed by a radical elimination. This radical process has opened up the possibilities for the development of new superoxide mediated synthetic methodologies using KOtBu as the single electron reductant.
ChemistrySelect published new progress about Aromatic alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, SDS of cas: 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts