Chen, Daoqian; Lu, Long; Shen, Qilong published the artcile< [Ag(bpy)(PPhtBu2)(OCF3)]: a stable nucleophilic reagent for chemoselective and stereospecific trifluoromethoxylation of secondary alkyl nosylates>, SDS of cas: 6290-03-5, the main research area is alkyl nosylate bipyridyl phosphinyl trifluoromethoxy silver preparation trifluoromethoxylation; trifluoromethoxy alkane enantioselective chemoselective preparation.
The development of a thermally stable and light-insensitive nucleophilic trifluoromethoxylative reagent [Ag(bpy)(PPhtBu2)(OCF3)], which was synthesized in high yields via a three-step one-pot process from easily available trifluoromethyl triflate (TFMT) and AgF at room temperature, was described. The high reactivity of reagent [Ag(bpy)(PPhtBu2)(OCF3)] was demonstrated by its high yielding chemoselective and stereospecific SN2-type trifluoromethoxylation with secondary alkyl nosylates.
Organic Chemistry Frontiers published new progress about Aliphatic alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 6290-03-5 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H10O2, SDS of cas: 6290-03-5.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts