Bheeter, Linus P.; Henrion, Mickael; Brelot, Lydia; Darcel, Christophe; Chetcuti, Michael J.; Sortais, Jean-Baptiste; Ritleng, Vincent published the artcile< Hydrosilylation of aldehydes and ketones catalyzed by an N-heterocyclic carbene-nickel hydride complex under mild conditions>, Safety of (1-Methyl-1H-pyrrol-2-yl)methanol, the main research area is nitrogen heterocyclic carbene nickel hydride preparation mol crystal structure; aldehyde hydrosilylation nitrogen heterocyclic carbene nickel hydride complex catalyst; ketone hydrosilylation nitrogen heterocyclic carbene nickel hydride complex catalyst; alc preparation.
Half-sandwich N-heterocyclic carbene (NHC)-nickel complexes of the general formula [Ni(NHC)ClCp1] (Cp1 = Cp, Cp*) efficiently catalyze the hydrosilylation of aldehydes and ketones at room temperature in the presence of a catalytic amount of sodium triethylborohydride and thus join the fairly exclusive club of well-defined nickel(II) catalyst precursors for the hydrosilylation of carbonyl functionalities. Of notable interest is the isolation of an intermediate nickel hydride complex that proved to be the real catalyst precursor.
Advanced Synthesis & Catalysis published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 52160-51-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C6H9NO, Safety of (1-Methyl-1H-pyrrol-2-yl)methanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts