Ai, Han-Jun; Yuan, Yang; Wu, Xiao-Feng published the artcile< Ruthenium pincer complex-catalyzed heterocycle compatible alkoxycarbonylation of alkyl iodides: substrate keeps the catalyst active>, Safety of 2-(Phenylthio)ethanol, the main research area is ester preparation; alkyl iodide alc carbon monoxide alkoxycarbonylation ruthenium pincer catalyst.
In this work, a pincer ruthenium pincer complex-catalyzed heterocycle compatible alkoxycarbonylation of alkyl iodides using alcs. and carbon monoxide to afford esters I [R = iPr, tBu, Ph, etc.; R1 = tBu, cyclopentyl, (CH2)3Ph, etc.] was reported. Benefitting from the pincer ligand, a variety of heterocycles, such as thiophenes, morpholine, unprotected indoles, pyrrole, pyridine, pyrimidine, furan, thiazole, pyrazole, benzothiadiazole, and triazole, were compatible in this protocol.
Chemical Science published new progress about Alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Safety of 2-(Phenylthio)ethanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts