《Exploring AIE luminogens as stickers to construct self-healing ionomers and as probes to detect the microscopic healing dynamics》 was written by Gu, Shiyu; Wang, Hao; Zhang, Hao; Peng, Yan; Zhang, Linjun; Zhang, Junqi; Zheng, Jing; Wu, Jinrong. Application In Synthesis of 3-Bromopropan-1-ol And the article was included in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2021. The article conveys some information:
In spite of considerable progress in self-healing polymers, detecting the healing kinetics and its underlying mol. mechanism is still in the early development stage. Herein, we design a self-healing ionomer by grafting AIEgens (PyTPE) as sticky groups onto a bromo-matrix (PBMB). The ionomer shows good mech. properties (15 MPa, 300%) and crack healing efficiency at room temperature Interestingly, the grafted AIEgen stickers enable us to quantify the healing kinetics and its underlying microscopic structural change through the evolution of fluorescence intensity induced by the AIE effect. In addition, a 2D correlation anal. indicates that the decoupled ionic moieties move first to recombine again during the healing process, finally leading to the reconstruction of a transient network and macro-healing. Therefore, this work offers a fluorescence-based method to study the microscopic self-healing mechanism of ionomers during damage and healing processes. In the experimental materials used by the author, we found 3-Bromopropan-1-ol(cas: 627-18-9Application In Synthesis of 3-Bromopropan-1-ol)
3-Bromopropan-1-ol(cas: 627-18-9) was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. Furthermore, it was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.Application In Synthesis of 3-Bromopropan-1-ol
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