Xiang, Ming; Luo, Guoshun; Wang, Yuankai; Krische, Michael J. published the artcile< Enantioselective iridium-catalyzed carbonyl isoprenylation via alcohol-mediated hydrogen transfer>, Category: alcohols-buliding-blocks, the main research area is methylenealkenol preparation enantioselective; primaryl alc methylenebutenyl carbonate isoprenylation iridium catalyst; aldehyde methylenebutenyl carbonate isoprenylation iridium catalyst.
Highly enantioselective iridium catalyzed carbonyl (2-vinyl)allylation or “”isoprenylation”” was developed for the synthesis of methylenealkenols I [R = cyclopropyl, 2-FC6H4, 2-thienyl, etc.] via hydrogen auto-transfer or 2-propanol-mediated reductive coupling of primary alcs. or aldehydes, resp. with tert-butyl-2-methylenebut-3-enyl carbonate. Using this method, asym. total syntheses of the terpenoid natural products, (+)-ipsenol and (+)-ipsdienol were also achieved.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenyl alcohols Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 6290-03-5 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H10O2, Category: alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts