Wang, Bao; Han, Xu; Li, Jian; Li, Chunpu; Liu, Hong published the artcile< Sulfoximines-assisted Rh(III)-catalyzed C-H activation and intramolecular annulation for the synthesis of fused isochromeno-1,2-benzothiazines scaffolds under room temperature>, COA of Formula: C8H10OS, the main research area is isochromenobenzothiazine preparation; phenylsulfoximide diazoisochroman imine annulation carbon hydrogen activation rhodium catalyst; C–H activation; benzothiazine; rhodium.; sulfoximide.
A mild and facile Cp*Rh(III)-catalyzed C-H activation and intramol. cascade annulation protocol has been proposed for the furnishing of highly fused isochromeno-1,2-benzothiazines I (R1 = H, 2-Me, 2-F, 4-Br, 3-OMe, (CH2)4, etc.; R2 = Me, Et, Ph, Bn, etc.; R3 = H, 10-Me,10-OMe, 11-Cl, 11-F, etc.) scaffolds using S-phenylsulfoximides R4C6H4S(O)(=NH)(R2) and 4-diazoisochroman-3-imine II (R5 = H, 7-Me, 6-OMe, 7-OMe, 6-Cl, etc.) as substrates under room temperature This method features diverse substituents and functional groups tolerance and relatively mild reaction conditions with moderate to excellent yields. Addnl., retentive configuration of sulfoximides in the conversion has been verified.
Molecules published new progress about C-H bond activation. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts