Shaw, Mukta; Kumar, Amit published the artcile< Additive-Free Gold(III)-Catalyzed Stereoselective Synthesis of 2-Deoxyglycosides Using Phenylpropiolate Glycosides as Donors>, Related Products of 4064-06-6, the main research area is deoxyglycoside stereoselective synthesis catalytic gold chloride; glycoside stereoselective glycosylation catalyzed gold disaccharide preparation phenylpropiolic acid; conformation transition state gold catalyzed stereoselective glycosylation disaccharide preparation; bifunctional donors; deoxy-phenylpropiolate; reusable and recyclable leaving group; stereoselective glycosylation.
Stereoselective synthesis of deoxyglycosides has been achieved from deoxy-phenylpropiolate glycosides (D-PPGs) using gold(III) salt as catalyst under external additive-free conditions. Under a simple catalytic system, D-PPGs reacted with a variety of sugar and non-sugar acceptors to produce major α-stereoselective O/N-deoxyglycosides in good to excellent yields and regenerate easily separable and reusable phenylpropiolic acid. Deoxy-PPGs containing armed and disarmed groups survived well under the optimized reaction conditions. In addition, the orthogonal nature of D-PPGs was showcased, and 1,1′-linked trehalose-type sugar was also synthesized.
Chemistry – An Asian Journal published new progress about Conformation. 4064-06-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H20O6, Related Products of 4064-06-6.
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