Wooding, Madelien;Rohwer, Egmont R.;Naude, Yvette published 《Determination of endocrine disrupting chemicals and antiretroviral compounds in surface water: A disposable sorptive sampler with comprehensive gas chromatography – Time-of-flight mass spectrometry and large volume injection with ultra-high performance liquid chromatography-tandem mass spectrometry》 in 2017. The article was appeared in 《Journal of Chromatography A》. They have made some progress in their research.Application of 80-46-6 The article mentions the following:
Many rural dwellers and inhabitants of informal settlements in South Africa are without access to treated water and collect untreated water from rivers and dams for personal use. Endocrine disrupting chems. (EDCs) have been detected in surface water and wildlife of South Africa. EDCs are often present in complex environmental matrixes at ultra-trace levels complicating detection thereof. We report a simplified multi-residue approach for the detection and quantification of EDCs, emerging EDCs, and antiretroviral drugs in surface water. A low cost (less than one US dollar), disposable, sorptive extraction sampler was prepared inhouse. The disposable samplers consisted of polydimethylsiloxane (PDMS) tubing fashioned into a loop which was then placed in water samples to concentrate EDCs and emerging pollutants. The PDMS samplers were thermally desorbed directly in the inlet of a GC, thereby eliminating the need for expensive consumable cryogenics. Comprehensive gas chromatog. coupled to time-of-flight mass spectrometry (GCxGC-TOFMS) was used for compound separation and identification. Linear retention indexes of EDCs and emerging pollutants were determined on a proprietary Crossbond phase Rtx–CLPesticides II GC capillary column. In addition, large volume injection of surface water into an ultra-performance liquid chromatograph tandem mass spectrometer (UPLC-MS/MS) was used as complementary methodol. for the detection of less volatile compounds Large volume injection reduced tedious and costly sample preparation steps. Limits of detection for the GC method ranged from 1 to 98 pg/l and for the LC method from 2 to 135 ng/l. Known and emerging EDCs such as pharmaceuticals, personal care products and pesticides, as well as the antiretroviral compounds, efavirenz and nevirapine, were detected in surface water from South Africa at concentration levels ranging from 0.16 ng/l to 227 ng/l.4-tert-Amylphenol (cas: 80-46-6) were involved in the experimental procedure.
4-tert-acylphenol (cas:80-46-6) contains hydroxyl group.Some low molecular weight alcohols of industrial importance are produced by the addition of water to alkenes. Ethanol, isopropanol, 2-butanol, and tert-butanol are produced by this general method. Application of 80-46-6
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