Liu, Ruzhang; Zhang, Yuanyuan; Xu, Jun published the artcile< Selective hydroboration of equilibrating allylic azides>, Electric Literature of 627-27-0, the main research area is azido boronic ester preparation pinacolborane oxidation; allylic azide hydroboration iridium catalyst.
The iridium(I)-catalyzed hydroboration of equilibrating allylic azides RCH:CHCH2N3 (R = pentyl, cyclohexylmethyl, 3-(pyrrol-1-yl)propyl, etc.) is reported to provide only the anti-Markovnikov products RCH(N3)CH2CH2OH of alk-1-ene isomers RCH(N3)CH:CH2 in good yields and with good functional group tolerance.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation) (azido-). 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, Electric Literature of 627-27-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts