Chen, Zewei; Lv, Kang; Yuan, Taoyue; Zhang, Xuguang; Yao, Weiwei; Ma, Mengtao published the artcile< Electrochemical hydroboration of carbonyl compounds>, Computed Properties of 403-41-8, the main research area is aryl alkyl alc preparation; boronic ester preparation regioselective green chem hydrolysis; carbonyl compound tetramethyl dioxaborolane electrochem hydroboration.
A green and sustainable electrochem. hydroboration of carbonyl compounds RC(O)R1 (R = Bu, Ph, cyclohexyl, pyridin-4-yl, etc.; R1 = H, Me, Ph, i-Pr, 2-fluorophenyl) with HBpin has been reported for the first time. Under catalyst-free and additive-free mild reaction conditions the corresponding boronic esters RR1CHOBpin were obtained in excellent yields via the simple electrochem. hydroboration of various aldehydes and ketones with HBpin at room temperature The scale-up reaction demonstrated potential practical applications. A plausible reaction mechanism was proposed based on the corresponding deuterium-labeling, radical inhibition and cyclic voltammetry experiments
Dalton Transactions published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Computed Properties of 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts