Category: alcohols-buliding-blocks《A star-shaped solid composite electrolyte containing multifunctional moieties with enhanced electrochemical properties for all solid-state lithium batteries》 was published in 2018. The authors were Zhang, Jinfang;Ma, Cheng;Hou, Hua;Li, Xiaofeng;Chen, Libao;Ivey, Douglas G.;Wei, Weifeng, and the article was included in《Journal of Membrane Science》. The author mentioned the following in the article:
Limited ionic conduction and poor solid/solid interfacial stability are crucial characteristics that impede the practical application of solid polymeric electrolytes. Herein, a star-shaped solid composite electrolyte (SCE) containing multifunctional components, including anion-trapping boron moieties (B-PEGMA), poly(ethylene glycol)methyl ether methacrylate (PEGMEM) and octavinyl octasilsesquioxane (OV-POSS) nanofiller, was developed via a simple free radical polymerization method. The unique star-shaped structure induced by OV-POSS is beneficial to increasing the movement of polymer chains and forming continuously interconnected ion-conducting channels and the boron moieties can promote lithium salt dissociation and increase the effective transmission of Li+ in the electrolyte. This SCE exhibits an extremely high ionic conductivity of 3.44 × 10-4 S cm-1 and a high Li ion transference number of 0.58 at 25°C, as well as excellent interfacial compatibility with the Li electrode leading to excellent rate performance and good cyclic stability in all-solid-state Li batteries. To complete the study, the researchers used 2,5-Dimethyl-2,5-hexanediol (cas: 110-03-2) .
2,5-Dimethyl-2,5-hexanediol(cas:110-03-2) is used as an intermediate in the preparation of 2.5-Dimethyl-2.5-bis(tertbutyl-peroxy)hexane. It is also used in the synthesis of six- and seven-membered heterocyclic boron compounds.Category: alcohols-buliding-blocks
Reference:
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