Liebold, Martin;Sharikow, Eugen;Seikel, Elisabeth;Trombach, Lukas;Harms, Klaus;Zimcik, Petr;Novakova, Veronika;Tonner, Ralf;Sundermeyer, Joerg published 《An experimental and computational study on isomerically pure, soluble azaphthalocyanines and their complexes and boron azasubphthalocyanines of a varying number of aza units》 in 2018. The article was appeared in 《Organic & Biomolecular Chemistry》. They have made some progress in their research.Related Products of 110-03-2 The article mentions the following:
Herein, the authors present a series of isomerically pure, peripherally alkyl substituted, soluble and low aggregating azaphthalocyanines as well as their new, smaller hybrid homologs, azasubphthalocyanines. The focus lies on the effect of the systematically increasing number of aza building blocks [-N=] replacing the non-peripheral [-CH=] units and their influence on the phys. and photophys. properties of these chromophores. The absolute and relative HOMO-LUMO energies of azaphthalocyanines were analyzed using UV-visible and CV and compared to the d. functional theory calculations (B3LYP, TD-DFT). The lowering of the HOMO level is revealed as the determining factor for the trend in the adsorption energies by electronic structure anal. Crystals of substituted subphthalocyanines, N2-Pc*H2 and N4-[Pc*Zn·H2O], were obtained out of DCM. For the synthesis of the valuable tetramethyltetralin phthalocyanine building block a new highly efficient synthesis involving a nearly quant. CoII catalyzed aerobic autoxidation step is introduced replacing inefficient KMnO4/pyridine as the oxidant. And 2,5-Dimethyl-2,5-hexanediol (cas: 110-03-2) was used in the research process.
2,5-Dimethyl-2,5-hexanediol(cas:110-03-2) is used as an intermediate in the preparation of 2.5-Dimethyl-2.5-bis(tertbutyl-peroxy)hexane. It is also used in the synthesis of six- and seven-membered heterocyclic boron compounds.Related Products of 110-03-2
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts