Alfonzo, Edwin; Hande, Sudhir M. published the artcile< Photoredox and Weak Bronsted Base Dual Catalysis: Alkylation of α-Thio Alkyl Radicals>, Related Products of 699-12-7, the main research area is radical alkylation thioether photoredox Bronsted base dual catalysis.
We report the C-H activation of thioethers to α-thio alkyl radicals and their addition to electron-deficient olefins to afford alkylated products through dual photoredox and weak Bronsted base catalysis. Mechanistic studies are consistent with a two-step activation mechanism, where oxidation of thioethers to their corresponding sulfide radical cations by an acridinium photoredox catalyst is followed with deprotonation by trifluoroacetate to generate α-thio alkyl radicals and trifluoroacetic acid (TFA). Exptl. studies support the involvement of TFA in all subsequent steps leading to product formation.
ACS Catalysis published new progress about Alkenes, electron-deficient Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Related Products of 699-12-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts