Doiuchi, Daiki;Nakamura, Tatsuya;Hayashi, Hiroki;Uchida, Tatsuya published 《Non-Heme-Type Ruthenium Catalyzed Chemo- and Site-Selective C-H Oxidation》 in 2020. The article was appeared in 《Chemistry – An Asian Journal》. They have made some progress in their research.Recommanded Product: 78-69-3 The article mentions the following:
Herein, a Ru(II)(BPGA) complex that could be used to catalyze chemo- and site-selective C-H oxidation was developed. The described ruthenium complex was designed by replacing one pyridyl group on tris(2-pyridylmethyl)amine with an electron-donating amide ligand that was critical for promoting this type of reaction. More importantly, higher reactivities and better chemo-, and site-selectivities were observed for reactions using the cis-ruthenium complex rather than the trans-one. This reaction could be used to convert sterically less hindered methyne and/or methylene C-H bonds of a various organic substrates, including natural products, into valuable alc. or ketone products. To complete the study, the researchers used 3,7-Dimethyloctan-3-ol (cas: 78-69-3) .
3,7-Dimethyloctan-3-ol(cas:78-69-3) is a fatty alcohol that is 3-octanol substituted by methyl groups at positions 3 and 7.Recommanded Product: 78-69-3 Metabolite observed in cancer metabolism. It has a role as a human metabolite.
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts