Carestia, Anthony M.;Ravelli, Davide;Alexanian, Erik J. published 《Reagent-dictated site selectivity in intermolecular aliphatic C-H functionalizations using nitrogen-centered radicals》 in 2018. The article was appeared in 《Chemical Science》. They have made some progress in their research.SDS of cas: 78-69-3 The article mentions the following:
Reagent-dictated site selectivity to intermol. aliphatic C-H functionalization using nitrogen-centered amidyl radicals were introduced. Simple modifications of the amide lead to high levels of site selectivity in intermol. C-H functionalizations across a range of simple and complex substrates. DFT calculations demonstrate that the steric demand of the reacting nitrogen-centered radical is heavily affected by the substitution pattern of the starting amide. Optimization of transition state structures consistently indicated higher reagent-dictated steric selectivities using more hindered amides, consistent with exptl. results. The experimental procedure involved many compounds, such as 3,7-Dimethyloctan-3-ol (cas: 78-69-3) .
3,7-Dimethyloctan-3-ol(cas:78-69-3) is a fatty alcohol that is 3-octanol substituted by methyl groups at positions 3 and 7.SDS of cas: 78-69-3 Metabolite observed in cancer metabolism. It has a role as a human metabolite.
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts