Ai, Han-Jun;Zhang, Youcan;Zhao, Fengqian;Wu, Xiao-Feng published 《Rhodium-Catalyzed Carbonylative Synthesis of Aryl Salicylates from Unactivated Phenols》 in 2020. The article was appeared in 《Organic Letters》. They have made some progress in their research.SDS of cas: 599-64-4 The article mentions the following:
In the presence of RhCl3 and 1,2-bis(dicyclohexylphosphino)ethane (dcpe), phenols underwent carbonylative esterification reactions with CO mediated by TEMPO in 1.4-dioxane/toluene to yield aryl salicylates such as Ph salicylate. Under similar conditions, but using 1,3-bis(diphenylphosphino)propane as the ligand, di-Ph carbonate was obtained as the major product. The mechanism of the reaction was studied using the reactions of potential intermediates and using kinetic isotope effects.4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) were involved in the experimental procedure.
4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.SDS of cas: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts