COA of Formula: C14H14O2《Amine Catalysis for the Organocatalytic Diboration of Challenging Alkenes》 was published in 2016. The authors were Farre, Albert;Soares, Kaline;Briggs, Rachel A.;Balanta, Angelica;Benoit, David M.;Bonet, Amadeu, and the article was included in《Chemistry – A European Journal》. The author mentioned the following in the article:
The generation of in situ sp2-sp3 diboron adducts has revolutionized the synthesis of organoboranes. Organocatalytic diboration reactions have represented a milestone in terms of unpredictable reactivity of these adducts. However, current methodologies have limitations in terms of substrate scope, selectivity and functional group tolerance. Here a new methodol. based on the use of simple amines as catalyst is reported. This methodol. provides a completely selective transformation overcoming current substrate scope and functional/protecting group limitations. Mechanistic studies have been included in this report. To complete the study, the researchers used rel-(1R,2S)-1,2-Diphenylethane-1,2-diol (cas: 579-43-1) .
rel-(1R,2S)-1,2-Diphenylethane-1,2-diol(cas: 579-43-1 COA of Formula: C14H14O2) has been used in the preparation of trans-methyl meso-hydrobenzoin phosphite.
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