Application In Synthesis of 7748-36-9, In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl functional group (−OH) bound to a saturated carbon atom. 7748-36-9, name is Oxetan-3-ol, An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula CnH2n+1OH.
Born, Max;Karaghiosoff, Konstantin;Klapoetke, Thomas M. research published 《 A GAP Replacement: Improved Synthesis of 3-Azidooxetane and Its Homopolymer Based on Sulfonic Acid Esters of Oxetan-3-ol》, the research content is summarized as follows. In the field of energetic binders, only hydroxy-terminated glycidyl azide polymer (GAP) has found widespread application and prevailed in the market. However, oxiranes such as glycidyl azide (GA) allow two ring-opening modes during polymerization and thus lead to polymers of different termination causing inhomogeneous curing results. An elegant solution is the polymerization of 3-azidooxetane as only terminating primary hydroxyl groups are formed. Beyond this, poly(3-azidooxetane) and GAP are equal in other aspects due to the similar repetition unit. Since literature methods for the preparation of 3-azidooxetane either employed toxic solvents, gave low yields, or impurified product, or could not be reproduced, a new synthesis method was developed to afford pure material and satisfying yields. The syntheses of toluene- and methanesulfonic acid esters of oxetan-3-ol as precursors were also significantly improved in comparison to the literature and their mol. structures elucidated by single-crystal X-ray diffraction. The aforementioned compounds and poly(3-azidooxetane) were intensively studied by vibrational and multinuclear NMR spectroscopy (1H, 13C, 14N), differential scanning calorimetry, and elemental anal. The key compound, 3-azidooxetane, was compared to glycidyl azide regarding performance using the EXPLO5 V6.04 thermochem. code and their sensitivity toward external stimuli like shock and friction assessed according to BAM standard procedures.
Application In Synthesis of 7748-36-9, Oxetan-3-ol is a useful research compound. Its molecular formula is C3H6O2 and its molecular weight is 74.08 g/mol. The purity is usually 95%.
Oxetan-3-ol is a synthetic hydroxy compound with the chemical formula C6H12O3. It is an organic solvent that can be used in reactions involving vinyl alcohol and oxetane, such as ring-opening polymerization and cationic polymerization. Oxetan-3-ol has also been shown to react with ethyl bromoacetate to form the corresponding oxetane, which can be used as a bioisostere for chloropropane, a potential replacement for chlorofluorocarbons., 7748-36-9.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts