SDS of cas: 110-03-2In 2020, Duffy, Ian R.;Vasdev, Neil;Dahl, Kenneth published 《Copper(I)-Mediated 11C-Carboxylation of (Hetero)arylstannanes》. 《ACS Omega》published the findings. The article contains the following contents:
A novel copper-mediated carboxylation strategy of aryl- and heteroaryl-stannanes was described. The method served as a mild (i.e., 1 atm) carboxylation method using stable carbon dioxide and was transferable as a radiosynthetic approach for carbon-11-labeled aromatic and heteroaromatic carboxylic acids using sub-stoichiometric quantities of [11C]CO2. The methodol. was applied to the radiosynthesis of the retinoid X receptor agonist, [11C]bexarotene, with a decay-corrected radiochem. yield of 32 ± 5% and molar activity of 38 ± 23 GBq/μmol (n = 3).2,5-Dimethyl-2,5-hexanediol (cas: 110-03-2) were involved in the experimental procedure.
2,5-Dimethyl-2,5-hexanediol(cas:110-03-2) on heteropoly acid catalyzed dehydration yields cyclic ethers via stereospecific intramolecular SN2 mechanism. It reacts with nitriles in concentrated sulfuric acid to yield Δ1-pyrrolines.SDS of cas: 110-03-2
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts