Name: Dichloro(1,5-cyclooctadiene)platinum(II). The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphines. Author is Martin, M. Trinidad; Marin, Mario; Rama, Raquel J.; Alvarez, Eleuterio; Maya, Celia; Molina, Francisco; Nicasio, M. Carmen.
Bulky terphenyl phosphine ligands PMe2Ar’ (Ar’ = terphenyl group) facilitate the isolation of zero-valent bis-phosphine complexes of Ni, Pd and Pt. The former show coordination numbers greater than two in the solid state due to the existence of Ni-Carene interactions with the terphenyl fragment.
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