HPLC of Formula: 12080-32-9. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about [n]-Cyclo-9,9-dibutyl-2,7-fluorene (n=4, 5): Nanoring Size Influence in Carbon-Bridged Cyclo-para-phenylenes. Author is Sicard, Lambert; Lucas, Fabien; Jeannin, Olivier; Bouit, Pierre-Antoine; Rault-Berthelot, Joelle; Quinton, Cassandre; Poriel, Cyril.
For the last ten years, ring-shaped π-conjugated macrocycles possessing radially directed π-orbitals have been subject to intense research. The electronic properties of these rings are deeply dependent on their size. However, most studies involve the flagship family of nanorings: the cyclo-para-phenylenes. We report herein the synthesis and study of the first examples of cyclofluorenes possessing five constituting fluorene units. The structural, optical and electrochem. properties were elucidated by X-ray crystallog., UV-vis absorption and fluorescence spectroscopy, and cyclic voltammetry. By comparison with a shorter analog, we show how the electronic properties of [5]-cyclofluorenes are drastically different from those of [4]-cyclofluorenes, highlighting the key role played by the ring size in the cyclofluorene family.
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