Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 651780-02-8, is researched, SMILESS is CC(C)(C)OC(=O)N1N=CC2=CC(Br)=CC=C12, Molecular C12H13BrN2O2Journal, Article, Journal of the American Chemical Society called Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates, Author is Jouffroy, Matthieu; Primer, David N.; Molander, Gary A., the main research direction is photoredox nickel catalyzed coupling ammonium alkylsilicate hetero aryl bromide.Recommanded Product: 651780-02-8.
Single-electron transmetalation is recognized as an enabling technol. for the mild transfer of alkyl groups to transition metal catalysts in cross-coupling reactions. Hypercoordinate silicates represent a new and improved class of radical precursors because of their low oxidation potentials and the innocuous byproducts generated upon oxidation Herein, authors report the cross-coupling of secondary and primary ammonium alkylsilicates with (hetero)aryl bromides in good to excellent yields. The base-free conditions have exceptional protic group tolerance on both partners, permitting the cross-coupling of unprotected primary and secondary amines.
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