Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II). So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Phosphorus and Arsenic Atom Transfer to Isocyanides to Form π-Backbonding Cyanophosphide and Cyanoarsenide Titanium Complexes.
Decarbonylation along with E atom transfer from Na(OCE) (E = P, As) to an isocyanide coordinated to the tetrahedral TiII complex [(TptBu,Me)TiCl], yielded the [(TptBu,Me)Ti(η3-ECNAd)] species (Ad = 1-adamantyl, TptBu,Me- = hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borate). In the case of E = P, the cyanophosphide ligand displays nucleophilic reactivity toward Al(CH3)3; moreover, its bent geometry hints to a reduced Ad-NCP3- resonance contributor. The analogous and rarer mono-substituted cyanoarsenide ligand, Ad-NCAs3-, shows the same unprecedented coordination mode but with shortening of the N:C bond. As opposed to TiII, VII fails to promote P atom transfer to AdNC, yielding instead [(TptBu,Me)V(OCP)(CNAd)]. Theor. studies revealed the rare ECNAd moieties to be stabilized by π-backbonding interactions with the former TiII ion, and their assembly to most likely involve a concerted E atom transfer between Ti-bound OCE- to AdNC ligands when studying the reaction coordinate for E = P.
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