Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 7661-33-8, is researched, SMILESS is O=C1N(C2=CC=C(Cl)C=C2)CCC1, Molecular C10H10ClNOJournal, Organic Chemistry Frontiers called Selective cleavage and reconstruction of C-N/C-C bonds in saturated cyclic amines: tunable synthesis of lactams and functionalized acyclic amines, Author is He, Yan; Yang, Jintao; Zhang, Xinying; Fan, Xuesen, the main research direction is saturated cyclic amine cleavage functionalization tandem reaction; arylpyrrolidinone preparation; tetramethylpiperidinyl arylformamido alkanoate preparation.Formula: C10H10ClNO.
Selective cleavage and functionalization of C-N/C-C bonds in saturated cyclic amines under the promotion of oxoammonium salt and tert-Bu hydroperoxide in the presence of different additives was developed. To be specific, cascade cleavage and reconstruction of C-N and C-C bonds took place under acidic conditions to provide pyrrolidin-2-ones. Under basic conditions, on the other hand, selective cleavage and functionalization of C-C bonds occurred to afford multi-functionalized acyclic N-formal amines. In addition, studies for revealing the intriguing reaction mechanisms was also been performed.
In addition to the literature in the link below, there is a lot of literature about this compound(1-(4-Chlorophenyl)pyrrolidin-2-one)Formula: C10H10ClNO, illustrating the importance and wide applicability of this compound(7661-33-8).
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