Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Selective Synthesis of Conjugated Chiral Macrocycles: Sidewall Segments of (-)/(+)-(12,4) Carbon Nanotubes with Strong Circularly Polarized Luminescence. Author is Wang, Jinyi; Zhuang, Guilin; Chen, Muqing; Lu, Dapeng; Li, Zhe; Huang, Qiang; Jia, Hongxing; Cui, Shengsheng; Shao, Xiang; Yang, Shangfeng; Du, Pingwu.
C nanotubes (CNTs) have unusual phys. properties that are valuable for nanotechnol. and electronics, but the chem. synthesis of chirality- and diameter-specific CNTs and π-conjugated CNT segments is still a great challenge. Reported here are the selective syntheses, isolations, characterizations, and photophys. properties of 2 novel chiral conjugated macrocycles ([4]cyclo-2,6-anthracene; [4]CAn2,6), as (-)/(+)(12,4) C nanotube segments. These conjugated macrocyclic mols. were obtained using a bottom-up assembly approach and subsequent reductive elimination reaction. The hoop-shaped mols. can be directly viewed by a STM technique. Chiral enantiomers with (-)/(+) helicity of the [4]CAn2,6 were isolated by HPLC. The new tubular CNT segments exhibit large absorption and luminescence red shifts compared to the monomer unit. The C enantiomers also show strong circularly polarized luminescence (glum≈0.1). The results reported here expand the scope of materials design for bottom-up synthesis of chiral macrocycles and enrich existing knowledge of their optoelectronic properties.
In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II), illustrating the importance and wide applicability of this compound(12080-32-9).
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