Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 16588-26-4, is researched, Molecular C6H3BrClNO2, about Formation and rearrangement of ipso intermediates in aromatic free-radical chlorination reactions, the main research direction is ipso intermediate radical chlorination; rearrangement halonitrobenzene chlorination mechanism; nitrobenzene halo chlorination mechanism; transition state structure chlorination.Related Products of 16588-26-4.
Photoinitiated chlorination of p-ClC6H4NO2 (I) in CCl4 at room temperature produces mainly p-Cl2C6H4 (II) and some Cl3C6H3 (III). Reaction of p-BrC6H4NO2 (IV) under the same conditions also produces II and III plus a small amount of 2,4-Br(O2N)C6H3Cl (V). The presence of rearrangement product V and the greater III/II ratio from IV than from I are strong evidence for the formation and rearrangement of an ipso intermediate in these aromatic free-radical chlorinations.
Compound(16588-26-4)Related Products of 16588-26-4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(3-Bromo-4-chloronitrobenzene), if you are interested, you can check out my other related articles.
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts