Electric Literature of C8H12Cl2Pt. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Platinum(II) Complexes with Bis(pyrazolyl)borate Ligands: Increased Molecular Rigidity for Bidentate Ligand Systems. Author is Soellner, Johannes; Pinter, Piermaria; Stipurin, Sergej; Strassner, Thomas.
The structural motif of platinum(II) complexes bearing cyclometalating N-heterocyclic carbene ligands can be used to design deep-blue phosphors for application in organic light-emitting diodes. However, the photophys. properties of the resulting mols. are also highly dependent on the auxiliary ligand. These often allow mol. deformations in the excited state which contribute to non-radiative decay processes that diminish the attainable quantum yield. The use of bis(pyrazolyl)borate-based auxiliary ligands enforces a high mol. rigidity due to their unique geometry. The steric crowding in the coordination sphere inhibits deformation processes and results in highly efficient deep-blue platinum(II) emitters with CIE coordinates below (0.15; 0.15).
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