Name: Dichloro(1,5-cyclooctadiene)platinum(II). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about C-C* Platinum(II) Complexes with PtXPX Metallacycle Forming (X = N and S) Auxiliary Ligands: Synthesis, Crystal Structures, and Properties. Author is Stipurin, Sergej; Wurl, Felix; Strassner, Thomas.
The synthesis of cyclometalated NHC Pt(II) complexes with two types of P-containing ligands is reported. Different synthetic approaches were used for each compound class. Dithiophosphinate and iminophosphonamide ligands form four-membered PtXPX metallacycles with coordination by either S or N atoms (= X). The complexes are fully characterized, including two solid-state structures. Addnl., the photophys. and electrochem. properties were examined, and the results are rationalized by d. functional theory calculations
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