The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ) is researched.COA of Formula: C8H12Cl2Pt.Stipurin, Sergej; Strassner, Thomas published the article 《Phosphorescent Cyclometalated Platinum(II) Imidazolinylidene Complexes》 about this compound( cas:12080-32-9 ) in European Journal of Inorganic Chemistry. Keywords: phosphorescent cyclometalated platinum imidazolinylidene diketonate complex DFT uv vis; crystal structure mol cyclometalated platinum imidazolinylidene diketonate complex optimized; cyclometalated platinum imidazolinylidene diketonate complex preparation electrochem thermal decomposition. Let’s learn more about this compound (cas:12080-32-9).
We present the synthesis and characterization of six novel bidentate C-C* cyclometalated platinum(II) complexes derived from saturated N-heterocyclic carbene precursors, namely 1-aryl-3-methyl-1H-4,5-dihydroimidazolium salts. The title compounds were then synthesized by a multi-step reaction, which includes an in situ generation of the silver carbene complex, followed by transmetalation to platinum and subsequent introduction of the β-diketonate ligand. Structural characterization by NMR experiments and solid-state structures prove the cyclometalation and the saturated backbone of the NHC motif. Photophys. and electrochem. properties of the platinum(II) complexes were examined and studied in detail by DFT calculations The title compounds are strongly emissive at room temperature in the sky-blue region of the visible spectrum and show quantum yields of up to 71% in a PMMA matrix.
There is still a lot of research devoted to this compound(SMILES：C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-])COA of Formula: C8H12Cl2Pt, and with the development of science, more effects of this compound(12080-32-9) can be discovered.
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