Stipurin, Sergej; Wurl, Felix; Strassner, Thomas published the article 《C-C* Platinum(II) Complexes with PtXPX Metallacycle Forming (X = N and S) Auxiliary Ligands: Synthesis, Crystal Structures, and Properties》. Keywords: diazaphosphaplatinacycle four membered carbene complex preparation electrochem mol orbital; dithiaphosphaplatinacycle four membered carbene complex preparation electrochem mol orbital; crystal structure four membered diazaphosphaplatinacycle dithiaphosphaplatinacycle carbene complex; mol structure four membered diazaphosphaplatinacycle dithiaphosphaplatinacycle carbene complex.They researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:12080-32-9) here.
The synthesis of cyclometalated NHC Pt(II) complexes with two types of P-containing ligands is reported. Different synthetic approaches were used for each compound class. Dithiophosphinate and iminophosphonamide ligands form four-membered PtXPX metallacycles with coordination by either S or N atoms (= X). The complexes are fully characterized, including two solid-state structures. Addnl., the photophys. and electrochem. properties were examined, and the results are rationalized by d. functional theory calculations
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