Electric Literature of C8H12Cl2Pt. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Synthesis and catalytic performance of highly dispersed platinum nanoparticles supported on alumina via supercritical fluid deposition. Author is Jiang, Haoxi; Yao, Chuanxu; Wang, Yaodong; Zhang, Minhua.
Highly dispersed platinum nanoparticles (NPs) supported on alumina were prepared by supercritical fluid deposition (SFD) with the aid of co-solvent ethanol using inorganometallic Na2PtCl6·6H2O as Pt precursor. The mean Pt particle size (1.5 nm) was obtained at the optimized deposition conditions of 40°C and 110 bar and 3 h of deposition time. The catalysts were characterized by high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), CO diffuse reflectance IR Fourier transform spectroscopy (CO-DRIFTS), XPS, inductively coupled plasma optical emission spectrometry (ICP-OES) and hydrogen-oxygen titrations to investigate the structure-activity relationship. Compared with the catalyst prepared via an impregnation method, the Pt was highly dispersed to smaller particles for Pt/Al2O3 catalysts prepared by SFD and showed much higher catalytic activity of catalytic reforming of cyclohexane dehydrogenation.
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