So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Ji, Radhe Shyam; Raghuvanshi, Abhinav; Jha, Badrinath; Mathur, Pradeep researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Synthetic Route of C8H12Cl2Pt.They published the article 《Reactions of [Ru6(μ6–C)(C6H5CH3)(CO)14]: Synthesis of some new Ru-Pt carbonyl clusters and diphosphine substitution》 about this compound( cas:12080-32-9 ) in Journal of Organometallic Chemistry. Keywords: carbido ruthenium carbonyl cluster reaction platinum diphosphine; crystal mol structure carbido ruthenium carbonyl platinum diphosphine complex. We’ll tell you more about this compound (cas:12080-32-9).
Three new RuPt clusters [Ru6Pt(μ6-C)(C6H5CH3)(CO)13(COD)] (2), [Ru6Pt(μ6-C)(C6H5CH3)(CO)14(PPh3)] (3) and [Ru6Pt2(μ6-C)(C6H5CH3)(CO)13(PPh3)3] (4) were obtained from the reaction of [Ru6(μ6-C)(C6H5CH3)(CO)14] (1) with two different Pt precursors. Both 2 and 3 consists of a Ru6Pt cluster with face capped octahedron metal core, whereas, 4 has a unique Ru6Pt2 cluster core structure with doubly capped octahedron. Further, CO substitution behavior of 1 was studied with diphosphine ligands, which results in the formation of mono and bi substituted products, which also show the removal of the toluene cap by the dppe ligand. All the compounds were characterized structurally by x-ray diffraction anal.
There is still a lot of research devoted to this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-])Synthetic Route of C8H12Cl2Pt, and with the development of science, more effects of this compound(12080-32-9) can be discovered.
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