Month: February 2022

Application of 100-86-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 100-86-7, Name is 2-Methyl-1-phenyl-2-propanol, SMILES is CC(O)(C)CC1=CC=CC=C1, belongs to alcohols-buliding-blocks compound. In a article, author is Shi, Zhiqiang, introduce new discover of the category.

Exploring catalytic processes performed under natural conditions is interesting, but there remains a great challenge in developing highly efficient catalysts for natural oxidation of alcohols. Herein, we report a chloroplast-like catalyst comprised of photoactive carbon dots (CDs), catalytically active Pt nanoparticles, and amphiphilic nanotubes. Under simulated and real natural reaction conditions, our catalysts exhibited remarkable activity and long-term reusability for the oxidation of various alcohols, significantly outperforming that of other counterpart catalysts and reported thermal/photocatalytic systems. It was demonstrated that when the carbon dots and the amphiphilic nanotubes respectively played a role in the light-harvesting and the substrate transport the Pt/CDs heterointerface acted as the active center for the matter conversion. Such an elaborate cooperation, an advanced process in the photosynthesis of plant, contributed to the excellent catalytic performance. This contribution provides a new design concept for artificial photocatalysts, which is very promising for developing sustainable catalytic processes.

Application of 100-86-7, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 100-86-7 is helpful to your research.

Reference:
Alcohol – Wikipedia,
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Product Details of 105-13-5. Authors Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K in AMER CHEMICAL SOC published article about in [Yamamoto, Yuki; Ota, Miyuto; Kodama, Shintaro; Michimoto, Kazuki; Nomoto, Akihiro; Ogawa, Akiya] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan; [Furuya, Mitsunori; Kawakami, Kiminori] Mitsubishi Chem Corp, Sci & Innovat Ctr, Yokohama, Kanagawa 2278502, Japan in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A green method for the oxidation of alcohols to carboxylic acids was developed using a novel co-catalytic system based on gold, silver, and copper catalysts. This reaction system was conducted under atmospheric oxygen in water and mild conditions to selectively oxidize 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, as a building block for polyethylene furanoate, which is a 100% bio-based, future alternative to the petroleum-based polyethylene terephthalate. Furthermore, various primary alcohols were conveniently oxidized to their corresponding carboxylic acids in up to quantitative yields.

Product Details of 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K or send Email.

Reference:
Alcohol – Wikipedia,
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Name: (4-Methoxyphenyl)methanol. In 2021 CHEMSUSCHEM published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

Name: (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Alcohol – Wikipedia,
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I found the field of Chemistry very interesting. Saw the article Dual-Role Catalysis by Thiobenzoic Acid in C alpha-H Arylation under Photoirradiation published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Hamashima, Y (corresponding author), Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Thiobenzoic acid (TBA) can serve as a single-electron reducing agent under photoirradiation from a blue light-emitting diode, in the presence of appropriate electron acceptors, and the resulting sulfur-centered radical species undergoes hydrogen atom abstraction. This dual-role catalysis by TBA enables regioselectivie C alpha-H arylation of benzylamines, benzyl alcohols, and ethers, as well as dihydroimidazoles, with cyano(hetero)arenes in good yield, without the need for a transition-metal photocatalyst and/or synthetically elaborated organic dyes.

Welcome to talk about 105-13-5, If you have any questions, you can contact Kobayashi, F; Fujita, M; Ide, T; Ito, Y; Yamashita, K; Egami, H; Hamashima, Y or send Email.. Name: (4-Methoxyphenyl)methanol

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SDS of cas: 105-13-5. Recently I am researching about BIS(IMINO)PYRIDINE COBALT COMPLEXES; CHEMOSELECTIVE HYDROGENATION; IRON; EFFICIENT; SOLVENT; AMIDES; MILD; HYDROBORATION; ISOMERIZATION; INHIBITION, Saw an article supported by the CSIR, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]; MHRD; DST/INSPIRE fellowship [IF160793]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Base-metal catalysts Co1, Co2 and Co3 were synthesized from designed pincer ligands L-1, L-2 and L-3 having NNN donor atoms respectively. Co1, Co2 and Co3 were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures of Co1 and Co3. Catalysts Col, Co2 and Co3 were utilized to study the dehydrogenative activation of alcohols for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.

Welcome to talk about 105-13-5, If you have any questions, you can contact Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K or send Email.. SDS of cas: 105-13-5

Reference:
Alcohol – Wikipedia,
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Authors Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH in AMER CHEMICAL SOC published article about in [Wei, Dongyue; Yang, Peng; Yu, Chuanman; Zhao, Fengkai; Wang, Yilei; Peng, Zhihua] China Univ Petr East China, Coll Sci, Dept Chem, Qingdao 266580, Shandong, Peoples R China in 2021, Cited 51. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A manganese-catalyzed N-alkylation reaction of amines with alcohols via hydrogen autotransfer strategy has been demonstrated. The developed practical catalytic system including an inexpensive, nontoxic, commercially available MnCl2 or MnBr(CO) s as the metal salt and triphenylphosphine as a ligand provides access to diverse aromatic, heteroaromatic, and aliphatic secondary amines in moderate-to-high yields. In addition, this operationally simple protocol is scalable to the gram level and suitable for synthesizing heterocycles such as indole and resveratrol-derived amines known to be active for Alzheimer’s disease.

COA of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Wei, DY; Yang, P; Yu, CM; Zhao, FK; Wang, YL; Peng, ZH or send Email.

Reference:
Alcohol – Wikipedia,
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I found the field of Chemistry very interesting. Saw the article Fe Doped MIL-101/Graphene Nanohybrid for Photocatalytic Oxidation of Alcohols Under Visible-Light Irradiation published in 2021. Application In Synthesis of (4-Methoxyphenyl)methanol, Reprint Addresses Yang, ZW (corresponding author), Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Key Lab Ecofunct Polymer Mat,Minist Educ, Lanzhou 730070, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A novel photoactive porous material of GR/FeMIL-101 based on FeMIL-101 metal organic frameworks (MOFs) was successfully synthesized via a simple hydrothermal method. The structural and photoelectric properties of the GR/FeMIL-101 was analyzed by XRD, SEM, TEM, TGA, XPS, UV-vis DRS, FT-IR, PL and EIS methods. The photocatalytic performance for the selective oxidation of benzyl alcohol with GR/FeMIL-101 as catalysts was evaluated under visible light irradiation. The results showed that the GR/FeMIL-101 nanohybrid had better photocatalytic performance than both of FeMIL-101 and the pristine MIL-101. It was further found that the incorporation of Fe and MIL-101 caused valence fluctuations of Fe3+/Fe2+ which improved the absorption of visible-light and increased the separation efficiency of photogenerated charges. In addition, the combination of FeMIL-101 and GR could further promote the transfer rate of the photoelectrons. The mechanism of the reaction revealed that center dot O-2(-) was the dominating active specie in this reaction through active species trapping experiments. [GRAPHICS] .

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. Application In Synthesis of (4-Methoxyphenyl)methanol

Reference:
Alcohol – Wikipedia,
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An article Mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies for boosting photocatalytic selective conversion of aromatic alcohols WOS:000644065100024 published article about EXPOSED 001 FACETS; SOOT OXIDATION ACTIVITY; VISIBLE PHOTOCATALYST; DOPED TIO2; PERCENTAGE; NANOCOMPOSITES; PERFORMANCE; NANOSHEETS; CATALYSTS; CRYSTALS in [Li, Dianfeng; Wang, Jinguo; Xu, Fengxia; Zhang, Nianchen; Men, Yong] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China in 2021, Cited 46. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Selective conversion of aromatic alcohols to value-added chemicals is becoming an emerging research hotspot in heterogeneous photocatalysis, but its critical challenge is how to construct highly efficient photocatalysts. Herein, mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies have been fabricated by a facile hydrothermal route, showing remarkably boosted photoactivity for selective conversion of aromatic alcohols to carbonyl compounds in water medium under visible-light irradiation. Results attest that the remarkably boosted photoactivity was mainly correlated with the strong synergetic effect of exposed (001) facets, Ti3+ self-doping, and surface oxygen vacancies, leading to the enhanced reactant (aromatic alcohols and O-2) activation via the high surface energy of (001) facets, the improved visible-light absorbance via the intrinsic band gap narrowing, and the escalated photoelectron-hole separation efficiency via Ti3+ and surface oxygen vacancies acting as electron sinks. Meanwhile, a plausible photocatalytic mechanism for selective conversion of aromatic alcohols to carbonyl compounds has been elucidated in detail based on active species identified by capture experiments. It is hoped that this work can deliver some new insights into the rational design of highly efficient photocatalysts applied in future green organic selective transformation reactions.

Welcome to talk about 105-13-5, If you have any questions, you can contact Li, DF; Wang, JG; Xu, FX; Zhang, NC; Men, Y or send Email.. COA of Formula: C8H10O2

Reference:
Alcohol – Wikipedia,
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Recently I am researching about SOLUBLE RECEPTOR TIE-2; CARDIOVASCULAR MORTALITY; ANGPTL4; DISEASE; RISK; ANGIOGENESIS; BIOMARKER; EVENTS, Saw an article supported by the . Published in WILEY in HOBOKEN ,Authors: Aarsetoy, R; Ueland, T; Aukrust, P; Michelsen, AE; de la Fuente, RL; Ponitz, V; Brugger-Andersen, T; Grundt, H; Staines, H; Nilsen, DWT. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Application In Synthesis of (4-Methoxyphenyl)methanol

Background Plasma levels of angiopoietin-2 (ANGPT2) and angiopoietin-like 4 protein (ANGPTL4) reflect different pathophysiological aspects of cardiovascular disease. We evaluated their association with outcome in a hospitalized Norwegian patient cohort (n = 871) with suspected acute coronary syndrome (ACS) and validated our results in a similar Argentinean cohort (n = 982). Methods A cox regression model, adjusting for traditional cardiovascular risk factors, was fitted for ANGPT2 and ANGPTL4, respectively, with all-cause mortality and cardiac death within 24 months and all-cause mortality within 60 months as the dependent variables. Results At 24 months follow-up, 138 (15.8%) of the Norwegian and 119 (12.1%) of the Argentinian cohort had died, of which 86 and 66 deaths, respectively, were classified as cardiac. At 60 months, a total of 259 (29.7%) and 173 (17.6%) patients, respectively, had died. ANGPT2 was independently associated with all-cause mortality in both cohorts at 24 months [hazard ratio (HR) 1.27 (95% confidence interval (CI), 1.08-1.50) for Norway, and HR 1.57 (95% CI, 1.27-1.95) for Argentina], with similar results at 60 months [HR 1.19 (95% CI, 1.05-1.35) (Norway), and HR 1.56 (95% CI, 1.30-1.88) (Argentina)], and was also significantly associated with cardiac death [HR 1.51 (95% CI, 1.14-2.00)], in the Argentinean population. ANGPTL4 was significantly associated with all-cause mortality in the Argentinean cohort at 24 months [HR 1.39 (95% CI, 1.15-1.68)] and at 60 months [HR 1.43 (95% CI, 1.23-1.67)], enforcing trends in the Norwegian population. Conclusions ANGPT2 and ANGPTL4 were significantly associated with outcome in similar ACS patient cohorts recruited on two continents. Clinical Trial Registration ClinicalTrials.gov Identifier: NCT00521976. ClinicalTrials.gov Identifier: NCT01377402.

Application In Synthesis of (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Authors Hu, M; Jiang, Y; Sun, N; Hu, BX; Shen, ZL; Hu, XQ; Jin, LQ in ROYAL SOC CHEMISTRY published article about C BOND FORMATION; ALPHA-ALKYLATION; UNACTIVATED AMIDES; KETONES; METHYLATION; ESTERS; ARYLACETONITRILES; FUNCTIONALIZATION; COMPLEXES; METHANOL in [Hu, Miao; Jiang, Yong; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu; Hu, Xinquan; Jin, Liqun] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China; [Jin, Liqun] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China in 2021, Cited 65. Application In Synthesis of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient method for the Ni-catalyzed C3-alkylation of indoles using readily available alcohols as the alkylating reagents has been developed. The alkylation was addressed with an air and moisture-stable binuclear nickel complex ligated by tetrahydroquinolin-8-one as the effective pre-catalyst. The newly developed transformation could accommodate a broad substrate scope including primary/secondary benzylic and aliphatic alcohols and substituted indoles. Mechanistic studies suggested that the reaction proceeds through a borrowing hydrogen pathway.

Application In Synthesis of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Hu, M; Jiang, Y; Sun, N; Hu, BX; Shen, ZL; Hu, XQ; Jin, LQ or send Email.

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