An article Iron-Catalyzed Regioselective Alkenylboration of Olefins WOS:000591817800001 published article about ENANTIOSELECTIVE ARYLBORATION; ALKENES; HYDROBORATION; SCOPE; DICARBOFUNCTIONALIZATION; MECHANISM; SECONDARY; ACCESS; BORYL in [Yu, Xiaolong; Zheng, Hongling; Zhao, Haonan; Lee, Boon Chong; Koh, Ming Joo] Natl Univ Singapore, Dept Chem, 12 Sci Dr 2, Singapore 117549, Singapore in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. SDS of cas: 105-13-5
The first examples of an iron-catalyzed three-component synthesis of homoallylic boronates from regioselective union of bis(pinacolato)diboron, an alkenyl halide (bromide, chloride or fluoride), and an olefin are disclosed. Products that bear tertiary or quaternary carbon centers could be generated in up to 87 % yield as single regioisomers with complete retention of the olefin stereochemistry. With cyclopropylidene-containing substrates, ring cleavage leading to trisubstituted E-alkenylboronates were selectively obtained. Mechanistic studies revealed reaction attributes that are distinct from previously reported alkene carboboration pathways.
Welcome to talk about 105-13-5, If you have any questions, you can contact Yu, XL; Zheng, HL; Zhao, HN; Lee, BC; Koh, MJ or send Email.. SDS of cas: 105-13-5
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts