Month: December 2021

Safety of (4-Methoxyphenyl)methanol. Authors Zhou, ZY; Xie, YN; Zhu, WZ; Zhao, HY; Yang, NJ; Zhao, GH in ELSEVIER published article about in [Zhou, Zhaoyu; Xie, Ya-Nan; Zhu, Wenze; Zhao, Hongying; Zhao, Guohua] Tongji Univ, Shanghai Tongji Hosp, Sch Chem Sci & Engn, Inst Translat Res, Shanghai 200092, Peoples R China; [Yang, Nianjun] Univ Siegen, Inst Mat Engn, D-57076 Siegen, Germany in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Hydrogen production can be promoted by replacing sluggish oxygen evolution reaction (OER) with a thermodynamically more favorable reaction, the primary oxidation reaction of benzyl alcohol to benzaldehyde. On a Bi2MoO6@TiO(2)NTA photocathode, the conversion of benzyl alcohol to benzaldehyde is realized with the selectivity of 100 %. This is originated from enhanced adsorption and activation of benzyl alcohol on this photoanode, as confirmed from tested by in situ FTIR techniques. The electrons generated during such a controllable and selective primary oxidation reaction is then utilized as the source for synergistical hydrogen production. The amount of generated hydrogen is then 5.5 times higher than that when OER is used. The efficiency for such hydrogen production is as high as 85 %. The proposed strategy combines solar energy and biomass for the efficient production of the valuable raw material – benzaldehyde as well as green energy source – hydrogen.

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Authors Nasresfahani, Z; Kassaee, MZ in WILEY published article about MCM-41 MOLECULAR-SIEVES; AROMATIC-AMINES; SILICA NANOPARTICLES; SOLVENT-FREE; OXIDATION; IRON; BENZYLATION; RUTHENIUM; AMINATION; SECONDARY in [Nasresfahani, Zahra; Kassaee, Mohamad Z.] Tarbiat Modares Univ, Dept Chem, POB 14155-175, Tehran, Iran in 2021, Cited 43. Quality Control of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A bimetallic catalyst (Ni/Cu-MCM-41) is prepared via co-condensation method. The latter is characterized by Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), diffuse reflectance spectroscopy (DRS), and nitrogen adsorption-desorption analysis. Catalytic performance of Ni/Cu-MCM-41 is probed in N-alkylation of amines with alcohols through a hydrogen autotransfer process. Noteworthy, this catalytic system appears very efficient for synthesis of a range of secondary and tertiary amines in good to excellent isolated yields. Moreover, the catalyst is successfully recovered and reused four times without notable decrease in its activity.

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Authors Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M in ROYAL SOC CHEMISTRY published article about in [Yoshida, Yasushi; Kukita, Mayu; Omori, Kazuki; Mino, Takashi; Sakamoto, Masami] Chiha Univ, Grad Sch Engn, Mol Chiral Res Ctr, Inage Ku, 1-33 Yayoi Cho, Chiba, Chiba 2638522, Japan in 2021, Cited 96. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Umpolung reactions of imines, especially the asymmetric reactions, have been extensively studied as they provide access to important chiral amines in an efficient manner. The reactions studied range from simple Michael reactions to several kinds of other reactions such as the aza-benzoin reaction, aza-Stetter reaction, addition with MBH carbonate, and Ir-catalysed allylation. Herein, we report the first umpolung alkylation reaction of alpha-iminoesters with alkyl halides mediated by iminophosphorane as an organic superbase. The desired products were obtained in up to 82% yield with almost perfect regioselectivities. The key to the regioselectivity of this reaction was the use of 4-trifluoromethyl benzyl imines as a substrate. The products were successfully derivatised into the more functionalised molecules in good yields.

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Luo, NH; Zhong, YH; Wen, HL; Shui, HL; Luo, RS in WILEY-V C H VERLAG GMBH published article about in [Luo, Nianhua; Zhong, Yuhong; Wen, Huiling; Shui, Hongling; Luo, Renshi] Gannan Med Univ, Sch Pharmaceut Sci, Ganzhou 341000, Jiangxi, Peoples R China in 2021, Cited 94. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Ketones are of great importance in synthesis, biology, and pharmaceuticals. This paper reports an iridium complexes-catalyzed cross-coupling of alcohols via hydrogen borrowing, affording a series of alpha-alkylated ketones in high yield (86 %-95 %) and chemoselectivities (>99 : 1). This methodology has the advantages of low catalyst loading (0.1 mol%) and environmentally benign water as the solvent. Studies have shown the amount of base has a great impact on chemoselectivities. Meanwhile, deuteration experiments show water plays an important role in accelerating the reduction of the unsaturated ketones intermediates. Remarkably, a gram-scale experiment demonstrates this methodology of iridium-catalyzed cross-coupling of alcohols has potential application in the practical synthesis of alpha-alkylated ketones.

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Category: alcohols-buliding-blocks. In 2021 J ORG CHEM published article about ALLYLIC ACETATES; MOLECULES in [Li, Shichao; Hou, Bo; Wang, Jianbo] Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China in 2021, Cited 40. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A palladium-catalyzed highly regio- and stereoselective allenic C-H oxidative coupling with alpha-diazo esters is developed. The reaction pathway involves allylic palladium carbene as the key intermediate, which is followed by a carbene migratory insertion process. The reaction proceeds efficiently under mild conditions without external base, providing substituted [3]dendralenes bearing various functional groups.

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Product Details of 105-13-5. I found the field of Chemistry very interesting. Saw the article Switchable Synthesis of alpha,alpha-Dihalomethyl and alpha,alpha,alpha-Trihalomethyl Ketones by Metal-Free Decomposition of Enaminone C=C Double Bond published in 2020, Reprint Addresses Liu, YY; Wan, JP (corresponding author), Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.

The novel free radical-based cleavage of the enaminone C=C double bond is realized by using N-halosuccinimides (NXS) in the presence of benzoyl peroxide (BPO) with mild heating, enabling the tunable synthesis of alpha,alpha-dihalomethyl ketones and alpha,alpha,alpha-trihalomethyl ketones under different reaction conditions. The formation of these divergent products involving featured C=C double bond cleavage requires no any metal reagent, and represents one more practical example on the synthesis of poly halogenated methyl ketones via the functionalization of carbon-carbon bond.

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COA of Formula: C8H10O2. Authors Sun, ZL; Yang, XL; Yu, XF; Xia, LH; Peng, YH; Li, Z; Zhang, Y; Cheng, JB; Zhang, KS; Yu, JQ in ELSEVIER published article about in [Sun, Zhaoli; Yang, Xiaolong; Xia, Linhong; Peng, Yanhua; Li, Zhuo; Zhang, Yan; Yu, Jianqiang] Qingdao Univ, Coll Chem & Chem Engn, 308 Ning Xia Rd, Qingdao 266071, Peoples R China; [Yu, Xue-Fang; Cheng, Jianbo] Yantai Univ, Sch Chem & Chem Engn, Lab Theoret & Computat Chem, 32 Qingquan Rd, Yantai 264005, Peoples R China; [Zhang, Kaisheng] Chinese Acad Sci, HFIPS, Inst Solid State Phys, Environm Mat & Pollut Control Lab, Hefei 230031, Peoples R China in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The recombination of photogenerated carriers seriously restricts their utilization efficiency in photocatalysis. Herein, surface oxygen vacancies (SOVs) were constructed in Pd-Bi2MoO6 interface to bridge ultra-low loading Pd cluster and Bi2MoO6 semiconductor (Pd/BMO-SOVs). It was found SOVs in Pd/Bi2MoO6-x serve as Electron Bridge to bridge ultra-low loading Pd cluster and Bi2MoO6-x, thus tremendously enhance utilization efficiency of photoexcited carriers and ultra-low loading Pd active sites for blue LED driven selective oxidation reaction. The Pd(0.05)/Bi2MoO6-SOVs exhibited 57.8 % conversion for selection oxidation of benzyl which are 6.5, 3.3 and 2.1 times higher than pristine Bi2MoO6, Bi2MoO6-x and Pd(0.05)/Bi2MoO6. Combined with theoretical calculations, SOVs was proposed as Electron Bridge to transfer photogenerated electrons from Bi2MoO6-x to ultra-low loading Pd clusters, thus greatly boosting separation and utilization efficiency of photogenerated electron-hole pairs.

COA of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Sun, ZL; Yang, XL; Yu, XF; Xia, LH; Peng, YH; Li, Z; Zhang, Y; Cheng, JB; Zhang, KS; Yu, JQ or send Email.

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Authors Padmanaban, S; Gunasekar, GH; Yoon, S in AMER CHEMICAL SOC published article about RUTHENIUM PINCER COMPLEX; POROUS ORGANIC POLYMER; SELECTIVE HYDROGENATION; HOMOGENEOUS HYDROGENATION; UNSATURATED ALDEHYDES; CYCLIC CARBONATES; ACTIVATED CARBON; SCALE SYNTHESIS; EFFICIENT; METHANOL in [Padmanaban, Sudakar; Yoon, Sungho] Chung Ang Univ, Dept Chem, Seoul 06974, South Korea; [Padmanaban, Sudakar] Seoul Natl Univ, Dept Chem, Seoul 08826, South Korea; [Gunasekar, Gunniya Hariyanandam] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul 136791, South Korea in 2021, Cited 95. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In this study, a commercially available homogeneous pincer-type complex, Ru-Macho, was directly heterogenized via the Lewis acid-catalyzed Friedel-Crafts reaction using dichloromethane as the cross-linker to obtain a heterogeneous, pincer-type Ru porous organometallic polymer (Ru-Macho-POMP) with a high surface area. Notably, Ru-Macho-POMP was demonstrated to be an efficient heterogeneous catalyst for the chemoselective hydrogenation of alpha,beta-unsaturated carbonyl compounds to their corresponding allylic alcohols using cinnamaldehyde as a model compound. The Ru-Macho-POMP catalyst showed a high turnover frequency (TOF = 920 h(-1)) and a high turnover number (TON = 2750), with high chemoselectivity (99%) and recyclability during the selective hydrogenation of alpha, beta-unsaturated carbonyl compounds.

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Recommanded Product: 105-13-5. Recently I am researching about ONE-POT SYNTHESIS; HETEROCYCLIZATION SYNTHESIS; NITROGEN-HETEROCYCLES; 3-COMPONENT SYNTHESIS; PURINE DERIVATIVES; AEROBIC OXIDATION; EFFICIENT; ALCOHOLS; ALDEHYDES; 1,3,5-TRIAZINES, Saw an article supported by the Department of Science and Technology (DST), New DelhiDepartment of Science & Technology (India) [YSS/2015/001554]. Published in WILEY in HOBOKEN ,Authors: Debnath, P; Sahu, G; De, UC. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A dehydrogenative coupling of N-uracil amidines with (hetero)aryl methanols has been developed, allowing for the facile synthesis of a broad range of structurally diverse pyrimidouracils. By applying [RuCl2(p-cymene)](2)/Cs2CO3 as an efficient catalytic system, the easily available, cheap (hetero)aryl methanols were firstly employed for oxidative insertion/C-H amination into the N-uracil amidines, providing highly functionalized pyrimido[4,5-d]pyrimidine-2,4-diones. Due to the better stability of alcohols than aldehydes, this synthetic protocol is applicable to a broad range of alcoholic substrates and does not required any protection during the whole preparation process. The presented protocol has the potential to prepare valuable products which cannot be accessed presently or extremely arduous to procure by following regular procedure. Hence, this is a remarkably improved protocol compared with the existing methodologies. The overall reaction sequence is an effective oxidation-imination-cyclization tandem process catalyzed by ruthenium catalyst.

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Computed Properties of C8H10O2. Authors Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Cavallo, Marzia; Arnodo, Davide; Mannu, Alberto; Blangetti, Marco; Prandi, Cristina; Baldino, Salvatore] Dipartimento Chim, Via P Giuria 7, I-10125 Turin, Italy; [Baratta, Walter] Univ Udine, Dipartimento DI4A, Via Cotonificio 108, I-33100 Udine, Italy in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The employment of easily affordable ruthenium(II)-complexes as pre-catalysts in the transfer hydrogenation of carbonyl compounds in deep eutectic media is described for the first time. The eutectic mixture tetrabutylammonium bromide/formic acid = 1/1 (TBABr/HCOOH = 1/1) acts both as reaction medium and hydrogen source. The addition of a base is required for the process to occur. An extensive optimization of the reaction conditions has been carried out, in terms of catalyst loading, type of complexes, H-2-donors, reaction temperature and time. The combination of the dimeric complex [RuCl(p-cymene)-mu-Cl](2) (0.01-0.05 eq.) and the ligand dppf (1,10-ferrocenediyl-bis(diphenylphosphine)ferrocene) in 1/1 molar ratio has proven to be a suitable catalytic system for the reduction of several and diverse aldehydes and ketones to their corresponding alcohols under mild conditions (40-60 degrees C) in air, showing from moderate to excellent tolerability towards different functional groups (halogen, cyano, nitro, phenol). The reduction of imine compounds to their corresponding amine derivatives was also studied. In addition, the comparison between the results obtained in TBABr/HCOOH and in organic solvents suggests a non-innocent effect of the DES medium during the process. (C) 2021 Elsevier Ltd. All rights reserved.

Computed Properties of C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S or send Email.

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