Recently I am researching about FREE AEROBIC OXIDATION; SUPPORTED TEMPO; ASYMMETRIC SULFOXIDATION; BLOCK-COPOLYMERS; CATALYST; METAL; EFFICIENT; DEHYDROGENATION; ALDEHYDES, Saw an article supported by the Zhejiang Provincial Key Research and Development Program [2021C01076]; Zhejiang Provincial Natural Science Foundation of ChinaNatural Science Foundation of Zhejiang Province [LY17B020013]; Fundamental Research Funds of Zhejiang Sci-Tech University [2019Q020]; Anhui Provinci a l Natura l Science FoundationNatural Science Foundation of Anhui Province [2008085QE249]; Anhui Provincial Innovation and Entrepreneurship Support Plan for Overseas Returnees [2019LCX023]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Wang, ML; Xu, ZK; Shi, Y; Cai, F; Qiu, JQ; Yang, G; Hua, Z; Chen, T. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Formula: C8H10O2
Polymeric nanoreactors in water fabricated by the self-assembly of amphiphilic copolymers have attracted much attention due to their good catalytic performance without using organic solvents. However, the disassembly and instability of relevant nanostructures often compromise their potential applicability. Herein, the preparation of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-containing nanoreactors by the self-assembly of amphiphilic bottle-brush copolymers has been demonstrated. First, a macromonomer having a norbornenyl polymerizable group was prepared by RAFT polymerization of hydrophobic and hydrophilic monomers. The macromonomer was further subjected to ring-opening metathesis polymerization to produce an amphiphilic bottlebrush copolymer. Further, TEMPO, as a catalyst, was introduced into the hydrophobic block through the activated ester strategy. Finally, TEMPO-functionalized polymeric nanoreactors were successfully obtained by self-assembly in water. The nanoreactors exhibited excellent catalytic activities in selective oxidation of alcohols in water. More importantly, the reaction kinetics showed that the turnover frequency is greatly increased compared to that of the similar nanoreactor prepared from liner copolymers under the same conditions. The outstanding catalytic activities of the nanoreactors from bottlebrush copolymers could be attributed to the more stable micellar structure using the substrate concentration effect. This work presents a new strategy to fabricate stable nanoreactors, paving the way for highly efficient organic reactions in aqueous solutions.
Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, ML; Xu, ZK; Shi, Y; Cai, F; Qiu, JQ; Yang, G; Hua, Z; Chen, T or send Email.. Formula: C8H10O2
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts