Month: November 2021

An article Switchable beta-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst WOS:000651063700005 published article about ALPHA-ALKYLATION; N-ALKYLATION; EFFICIENT CATALYSTS; BORROWING HYDROGEN; PINCER COMPLEXES; AROMATIC-AMINES; MANGANESE; KETONES; METHYLATION; IMINES in [Pandey, Bedraj; Xu, Shi; Ding, Keying] Middle Tennessee State Univ, Dept Chem, Murfreesboro, TN 37132 USA; [Ding, Keying] Middle Tennessee State Univ, Mol Biosci Program, Murfreesboro, TN 37132 USA in 2021, Cited 72. Name: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

beta-alkylation of secondary alcohols with primary alcohols to selectively generate alcohols by a well-defined Co catalyst is presented. Remarkably, a low catalyst loading of 0.7 mol % can be employed for the reaction. More significantly, this study represents the first Co-catalyzed switchable alcohol/ketone synthesis by simply manipulating the reaction parameters. In addition, the transformation is environmentally friendly, with water as the only byproduct.

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Product Details of 105-13-5. Authors Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA in WILEY-V C H VERLAG GMBH published article about in [Ruiz-Castaneda, Margarita; Santos, Lucia; Manzano, Blanca R.; Jalon, Felix A.] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim IRICA, Avda CJ Cela 10, Ciudad Real 13071, Spain; [Espino, Gustavo] Univ Burgos, Fac Ciencias, Dept Quim, Plaza Misael Banuelos S-N, Burgos 09001, Spain in 2021, Cited 107. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Deuterium labeling is an interesting process that leads to compounds of use in different fields. We describe the transfer hydrogenation of aldehydes and the selective C-1 deuteration of the obtained alcohols in D2O, as the only deuterium source. Different aromatic, alkylic and alpha,beta-unsaturated aldehydes were reduced in the presence of [RuCl(p-cymene)(dmbpy)]BF4, (dmbpy=4,4 ‘-dimethyl-2,2 ‘-bipyridine) as the pre-catalyst and HCO2Na/HCO2H as the hydrogen source. Moreover, furfural and glucose, were selectively reduced to the valuable alcohols, furfuryl alcohol and sorbitol. The processes were carried out in neat water or in a biphasic water/toluene system. The biphasic system allowed easy recycling, higher yields, and higher selective D incorporation (using D2O/toluene). The deuteration took place due to an efficient effective M-H/D+ exchange from D2O that allows the inversion of polarity of D+ (umpolung). DFT calculations that explain the catalytic behavior in water are also included.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA or concate me.. Product Details of 105-13-5

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Authors Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K in ROYAL SOC CHEMISTRY published article about in [Kon, Yoshihiro; Nakashima, Takuya; Yada, Akira; Fujitani, Tadahiro; Onozawa, Shun-ya; Kobayashi, Shu; Sato, Kazuhiko] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, Tsukuba, Ibaraki 3058565, Japan; [Kobayashi, Shu] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan in 2021, Cited 41. Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The oxidation of alcohols to aldehydes is a powerful reaction pathway for obtaining valuable fine chemicals used in pharmaceuticals and biologically active compounds. Although many oxidants can oxidize alcohols, only a few hydrogen peroxide oxidations can be employed to continuously synthesize aldehydes in high yields using a liquid-liquid two-phase flow reactor, despite the possibility of the application toward a safe and rapid multi-step synthesis. We herein report the continuous flow synthesis of (E)-cinnamaldehyde from (E)-cinnamyl alcohol in 95%-98% yields with 99% selectivity for over 5 days by the selective oxidation of hydrogen peroxide using a catalyst column in which Pt is dispersed in SiO2. The active species for the developed selective oxidation is found to be zero-valent Pt(0) from the X-ray photoelectron spectroscopy measurements of the Pt surface before and after the oxidation. Using Pt black diluted with SiO2 as a catalyst to retain the Pt(0) species with the optimal substrate and H2O2 introduction rate not only enhances the catalytic activity but also maintains the activity during the flow reaction. Optimizing the contact time of the substrate with Pt and H2O2 using a flow reactor is important to proceed with the selective oxidation to prevent the catalytic H2O2 decomposition.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K or concate me.

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An article Dinuclear Copper(II) Complexes with N,O Donor Ligands: Partial Ligand Hydrolysis and Alcohol Oxidation Catalysis WOS:000651570800001 published article about SCHIFF-BASE COMPLEXES; AEROBIC OXIDATION; METAL-COMPLEXES; COORDINATION POLYMERS; CU-II; PEROXIDATIVE OXIDATION; DICOPPER(II) COMPLEX; SELECTIVE OXIDATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES in [Barma, Arpita; Bhattacharjee, Aradhita; Roy, Partha] Jadavpur Univ, Dept Chem, Kolkata 700032, India in 2021, Cited 115. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: (4-Methoxyphenyl)methanol

Two copper(II) complexes [Cu-2(L-1)(2)] (1) and [Cu-2(L-2)(2)] (2) where H2L1=2-hydroxy-3-((3-hydroxy-2,2-dimethylpropylimino)methyl)-5-methylbenzaldehyde and H2L2=2-hydroxy-3-(((1-hydroxypropan-2-yl)imino)methyl)-5-methylbenzaldehyde have been synthesized and used as catalysts in alcohol oxidation. 2,6-Diformyl-4-methylphenol (DFP) based Schiff-base ligands, 3,3 ‘-(2-hydroxy-5-methyl-1,3-phenylene)bis(methan-1-yl-1-ylidene)bis(azan-1-yl-1-ylidene)bis(2,2-dimethylpropan-1-ol) (H3L ‘) and 2,2 ‘-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methanylylidene))bis(azanylylidene))bis(propan-1-ol) (H3L ”), undergo partial hydrolysis to convert one of the azomethine groups to aldehyde group to give H2L1 and H2L2, and then react with copper(II) acetate to yield complex 1 and 2, respectively. These complexes have been characterized by standard methods such as elemental analysis, room temperature magnetic studies, FT-IR, UV-vis, ESI-mass spectral analyses, cyclic voltammogram, etc. The structures of dinuclear complexes with modified ligands have been confirmed by single crystal X-ray diffraction analysis. Complex 1 and 2 have been used as catalysts for the oxidation of benzyl alcohol, 4-methyl benzyl alcohol, 4-methoxy benzyl alcohol, 4-nitro benzyl alcohol and 4-bromo benzyl alcohol to the corresponding aldehyde as the sole product. Efficiency of the catalyst depends on the chain length and substitution on the chain of the ligand.

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Computed Properties of C8H10O2. Authors Ryan, RYM; Fernandez, A; Wong, Y; Miles, JJ; Cock, IE in NATURE RESEARCH published article about in [Ryan, Rachael Y. M.; Wong, Yide; Miles, John J.] James Cook Univ, Australian Inst Trop Hlth & Med AITHM, Cairns, Qld 4878, Australia; [Ryan, Rachael Y. M.; Wong, Yide; Miles, John J.] James Cook Univ, Ctr Mol Therapeut, Cairns 4878, Australia; [Ryan, Rachael Y. M.; Fernandez, Alejandra; Cock, Ian E.] Griffith Univ, Sch Environm & Sci, Brisbane, Qld 4111, Australia; [Wong, Yide; Miles, John J.] James Cook Univ, Ctr Trop Bioinformat & Mol Biol, Cairns 4878, Australia; [Fernandez, Alejandra; Cock, Ian E.] Griffith Univ, Environm Futures Res Inst, Brisbane, Qld 4111, Australia in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Bark from the Handroanthus impetiginosus (Mart. ex DC.) Mattos (Bignoniaceae) tree has long been used in traditional South American healing practises to treat inflammation. However, its anti-inflammatory activity has not been closely examined. Here we use chemical extraction, qualitative phytochemical examination, toxicity testing and quantitative examination of anti-inflammatory activity on human cells ex vivo. All extracts were found to be nontoxic. We found different extracts exhibited unique cytokine profiles with some extracts outperforming a positive control used in the clinic. These results verify the immunomodulatory activity of Handroanthus impetiginosus (Mart. ex DC.) Mattos (Bignoniaceae) tree bark-derived compounds. Collectively, combining a lack of toxicity and potency in human immune cells supports further fractionation and research.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Ryan, RYM; Fernandez, A; Wong, Y; Miles, JJ; Cock, IE or concate me.

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An article Synthesis of functionalized pyrimidouracils by ruthenium-catalyzed oxidative insertion of (hetero)aryl methanols into N-uracil amidines WOS:000587048900001 published article about ONE-POT SYNTHESIS; HETEROCYCLIZATION SYNTHESIS; NITROGEN-HETEROCYCLES; 3-COMPONENT SYNTHESIS; PURINE DERIVATIVES; AEROBIC OXIDATION; EFFICIENT; ALCOHOLS; ALDEHYDES; 1,3,5-TRIAZINES in [Debnath, Pradip] Maharaja Bir Bikram Coll, Dept Chem, Agartala 799004, Tripura, India; [Sahu, Gouranga] Ramkrishna Mahavidyalaya, Dept Chem, Unakoti, India; [De, Utpal C.] Tripura Univ, Dept Chem, Agartala, India in 2021, Cited 96. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A dehydrogenative coupling of N-uracil amidines with (hetero)aryl methanols has been developed, allowing for the facile synthesis of a broad range of structurally diverse pyrimidouracils. By applying [RuCl2(p-cymene)](2)/Cs2CO3 as an efficient catalytic system, the easily available, cheap (hetero)aryl methanols were firstly employed for oxidative insertion/C-H amination into the N-uracil amidines, providing highly functionalized pyrimido[4,5-d]pyrimidine-2,4-diones. Due to the better stability of alcohols than aldehydes, this synthetic protocol is applicable to a broad range of alcoholic substrates and does not required any protection during the whole preparation process. The presented protocol has the potential to prepare valuable products which cannot be accessed presently or extremely arduous to procure by following regular procedure. Hence, this is a remarkably improved protocol compared with the existing methodologies. The overall reaction sequence is an effective oxidation-imination-cyclization tandem process catalyzed by ruthenium catalyst.

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Authors Zhou, ZY; Xie, YN; Zhu, WZ; Zhao, HY; Yang, NJ; Zhao, GH in ELSEVIER published article about in [Zhou, Zhaoyu; Xie, Ya-Nan; Zhu, Wenze; Zhao, Hongying; Zhao, Guohua] Tongji Univ, Shanghai Tongji Hosp, Sch Chem Sci & Engn, Inst Translat Res, Shanghai 200092, Peoples R China; [Yang, Nianjun] Univ Siegen, Inst Mat Engn, D-57076 Siegen, Germany in 2021, Cited 55. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Hydrogen production can be promoted by replacing sluggish oxygen evolution reaction (OER) with a thermodynamically more favorable reaction, the primary oxidation reaction of benzyl alcohol to benzaldehyde. On a Bi2MoO6@TiO(2)NTA photocathode, the conversion of benzyl alcohol to benzaldehyde is realized with the selectivity of 100 %. This is originated from enhanced adsorption and activation of benzyl alcohol on this photoanode, as confirmed from tested by in situ FTIR techniques. The electrons generated during such a controllable and selective primary oxidation reaction is then utilized as the source for synergistical hydrogen production. The amount of generated hydrogen is then 5.5 times higher than that when OER is used. The efficiency for such hydrogen production is as high as 85 %. The proposed strategy combines solar energy and biomass for the efficient production of the valuable raw material – benzaldehyde as well as green energy source – hydrogen.

SDS of cas: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhou, ZY; Xie, YN; Zhu, WZ; Zhao, HY; Yang, NJ; Zhao, GH or concate me.

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Name: (4-Methoxyphenyl)methanol. Authors Pandey, VK; Tiwari, CS; Rit, A in AMER CHEMICAL SOC published article about in [Pandey, Vipin K.; Tiwari, Chandra Shekhar; Rit, Arnab] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India in 2021, Cited 56. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

AgSbF6 was developed as an effective catalyst for the hydroboration of various unsaturated functionalities (nitriles, alkenes, and aldehydes). This atom-economic chemoselective protocol works effectively under low catalyst loading, base- and solvent-free moderate conditions. Importantly, this process shows excellent functional group tolerance and compatibility with structurally and electronically diverse substrates (>50 examples). Mechanistic investigations revealed that the reaction proceeds via a radical pathway. Further, the obtained N,N-diborylamines were showcased to be useful precursors for amide synthesis.

Name: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Pandey, VK; Tiwari, CS; Rit, A or concate me.

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Quality Control of (4-Methoxyphenyl)methanol. Authors Zhang, YY; Liu, Q; Zhang, LY; Bao, YM; Tan, JY; Zhang, N; Zhang, JY; Liu, ZJ in ROYAL SOC CHEMISTRY published article about in [Zhang, Ying-Ying] Zhongyuan Univ Technol, Ctr Adv Mat Res, Zhengzhou 450007, Peoples R China; [Liu, Qing; Zhang, Lin-Yan; Bao, Yu-Mei; Tan, Jing-Yi; Zhang, Na; Zhang, Jian-Yong; Liu, Zhen-Jiang] Shanghai Inst Technol, Shanghai 201418, Peoples R China in 2021, Cited 82. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Three new Ni-II/Co-II-metal organic frameworks were self-assembled by the reaction of C-3 symmetric 1,3,5-tribenzoic acid (H3BTC) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine (4-TPT) ligands and Ni-II/Co-II salts under solvothermal conditions. Isomorphous MOF1 and MOF2 exhibit a 3D pillar-layer framework based on binuclear M-2(OH)(COO)(2) units connected by tritopic BTC3- and 4-TPT ligands with a novel (3,5)-connected topology net. MOF3 displays a 3-fold interpenetrated 3D network exhibiting a (3,4)-connected topology net. The porous MOF3 can reversibly take up I-2. The activated MOFs contain both Lewis acid (Ni-II center) and basic (uncoordinated pyridyl or carboxylic groups) sites, and act as bifunctional acid-base catalysts. The catalytic measurements demonstrate that the activated MOF3 exhibits good activities for benzyl alcohol oxidation and the Knoevenagel reaction and can be recycled and reused for at least four cycles without losing its structural integrity and high catalytic activity. Thus, the catalytic properties for the oxidation-Knoevenagel cascade reaction have also been studied.

Quality Control of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Zhang, YY; Liu, Q; Zhang, LY; Bao, YM; Tan, JY; Zhang, N; Zhang, JY; Liu, ZJ or concate me.

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Name: (4-Methoxyphenyl)methanol. Authors Aydin, BO; Anil, D; Demir, Y in WILEY-V C H VERLAG GMBH published article about in [Aydin, Busra O.; Anil, Derya] Ataturk Univ, Dept Chem, Fac Sci, Erzurum, Turkey; [Anil, Derya] Ataturk Univ, Tech Sci Vocat Sch, Dept Chem & Chem Proc Technol, Erzurum, Turkey; [Demir, Yeliz] Ardahan Univ, Nihat Delibalta Gole Vocat Sch, Dept Pharm Serv, Ardahan, Turkey in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Fused pyrimidines, especially pyrazolo[3,4-d]pyrimidines, are among the most preferred building blocks for pharmacology studies, as they exhibit a broad spectrum of biological activity. In this study, new derivatives of pyrazolo[3,4-d]pyrimidine were synthesized by alkylation of the N1 nitrogen atom. We synthesized 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine 2 from commercially available aminopyrazolopyrimidine 1 using N-iodosuccinimide as an iodinating agent. The synthesis of compound 2 started with nucleophilic substitution of 3-iodo-1H-pyrazolo[3,4-d]pyrimidin-4-amine with R-X (X: -OMs, -Br, -Cl), affording N-alkylated pyrazolo[3,4-d]pyrimidine. We performed this synthesis using a weak inorganic base and the mild temperature was also used for a two-step procedure to generate N-alkylated pyrazolo[3,4-d]pyrimidine derivatives. Also, all compounds were tested for their ability to inhibit acetylcholinesterase (AChE) and the human carbonic anhydrase (hCA) isoforms I and II, with K-i values in the range of 15.41 +/- 1.39-63.03 +/- 10.68 nM for AChE, 17.68 +/- 1.92-66.27 +/- 5.43 nM for hCA I, and 8.41 +/- 2.03-28.60 +/- 7.32 nM for hCA II. Notably, compound 10 was the most selective and potent CA I inhibitor with a significant selectivity ratio of 26.90.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Aydin, BO; Anil, D; Demir, Y or concate me.. Name: (4-Methoxyphenyl)methanol

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