Month: November 2021

In 2021 MICROPOR MESOPOR MAT published article about METAL-ORGANIC FRAMEWORKS; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; HIGHLY EFFICIENT; DRUG-DELIVERY; TOLUENE; ULTRASOUND; PERFORMANCE; AMIDATION; ALCOHOLS in [Karimi, Meghdad; Mohebali, Haleh; Sadeghi, Samira; Mahjoub, Alireza; Heydari, Akbar] Tarbiat Modares Univ, Chem Dept, POB 14155-4838, Tehran, Iran; [Safarifard, Vahid] Iran Univ Sci & Technol, Dept Chem, Tehran 1684613114, Iran in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

Ce-UiO-66 MOF, namely cerium-organic framework was prepared through a fast and efficient method under ultrasonic radiation. After preparation, it was identified using some different microscopic and spectroscopic techniques such as PXRD, FT-IR, TG/DTA, BET, BJH, and FE-SEM. The catalytic activity of Ce-UiO-66 MOF was checked in aerobic oxidation of methyl arenas, alcohols and styrene derivatives in a sustainable circumstance with no additives. Moreover, its catalytic activity was surveyed influenced by a number of variables in the ultrasonic synthesis method. Some parameters such as solvent, base, temperature, amount of the catalyst and time were also tested to optimize the aerobic oxidation reaction. After the 10th run, the recycled Ce-MOF showed an acceptable efficiency, which proved its high reusability and stability under optimized conditions. Furthermore, the Ce-UiO-66 was investigated structurally by PXRD method which demonstrated the catalyst stability after the aerobic oxidation reaction.

Welcome to talk about 105-13-5, If you have any questions, you can contact Karimi, M; Mohebali, H; Sadeghi, S; Safarifard, V; Mahjoub, A; Heydari, A or send Email.. Recommanded Product: 105-13-5

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SDS of cas: 105-13-5. Authors Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA in WILEY-V C H VERLAG GMBH published article about in [Ruiz-Castaneda, Margarita; Santos, Lucia; Manzano, Blanca R.; Jalon, Felix A.] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim IRICA, Avda CJ Cela 10, Ciudad Real 13071, Spain; [Espino, Gustavo] Univ Burgos, Fac Ciencias, Dept Quim, Plaza Misael Banuelos S-N, Burgos 09001, Spain in 2021, Cited 107. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Deuterium labeling is an interesting process that leads to compounds of use in different fields. We describe the transfer hydrogenation of aldehydes and the selective C-1 deuteration of the obtained alcohols in D2O, as the only deuterium source. Different aromatic, alkylic and alpha,beta-unsaturated aldehydes were reduced in the presence of [RuCl(p-cymene)(dmbpy)]BF4, (dmbpy=4,4 ‘-dimethyl-2,2 ‘-bipyridine) as the pre-catalyst and HCO2Na/HCO2H as the hydrogen source. Moreover, furfural and glucose, were selectively reduced to the valuable alcohols, furfuryl alcohol and sorbitol. The processes were carried out in neat water or in a biphasic water/toluene system. The biphasic system allowed easy recycling, higher yields, and higher selective D incorporation (using D2O/toluene). The deuteration took place due to an efficient effective M-H/D+ exchange from D2O that allows the inversion of polarity of D+ (umpolung). DFT calculations that explain the catalytic behavior in water are also included.

Welcome to talk about 105-13-5, If you have any questions, you can contact Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA or send Email.. SDS of cas: 105-13-5

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Formula: C8H10O2. Authors Song, JL; Hua, ML; Huang, X; Visa, A; Wu, TB; Fan, HL; Hou, MQ; Zhang, ZF; Han, BX in ROYAL SOC CHEMISTRY published article about in [Song, Jinliang; Hua, Manli; Huang, Xin; Wu, Tianbin; Fan, Honglei; Hou, Minqiang; Zhang, Zhaofu; Han, Buxing] Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China; [Hua, Manli; Huang, Xin; Han, Buxing] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China; [Visa, Aurelia] Romanian Acad, Inst Chem Timisoara, 24 M Viteazul Ave, Timisoara 300223, Romania in 2021, Cited 44. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The Meerwein-Ponndorf-Verley (MPV) reaction is an attractive approach to selectively reduce carbonyl groups, and the design of advanced catalysts is the key for these kinds of interesting reactions. Herein, we fabricated a novel zirconium organoborate using 1,4-benzenediboronic acid (BDB) as the precursor for MPV reduction. The prepared Zr-BDB had excellent catalytic performance for the MPV reduction of various biomass-derived carbonyl compounds (i.e., levulinate esters, aldehydes and ketones). More importantly, the number of borate groups on the ligands significantly affected the catalytic activity of the Zr-organic ligand hybrids, owing to the activation role of borate groups on hydroxyl groups in the hydrogen source. Detailed investigations revealed that the excellent performance of Zr-BDB was contributed by the synergetic effect of Zr4+ and borate. Notably, this is the first work to enhance the activity of Zr-based catalysts in MPV reactions using borate groups.

Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Song, JL; Hua, ML; Huang, X; Visa, A; Wu, TB; Fan, HL; Hou, MQ; Zhang, ZF; Han, BX or send Email.

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COA of Formula: C8H10O2. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

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Recommanded Product: 105-13-5. Authors Zhuang, XH; Shi, XY; Zhu, R; Sun, B; Su, WK; Jin, C in ROYAL SOC CHEMISTRY published article about in [Zhuang, Xiaohui; Sun, Bin; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou, Peoples R China; [Shi, Xiayue; Zhu, Rui; Su, WeiKe; Jin, Can] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou, Peoples R China in 2021, Cited 58. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A mild and metal-free protocol for visible-light induced intramolecular radical cyclization of N-allyl(propargyl)-2-bromo-2,2-difluoro-N-arylacetamide has been developed. This strategy showed excellent regioselectivity and simple operation to synthesize 4-substituted 3,3-difluoro-gamma-lactams with a broad substrate scope. Moreover, mechanistic studies revealed that this transformation proceeded through a cascade radical-type cyclization and hydrogen atom transfer process with PMDETA as a hydrogen-atom donor.

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Product Details of 105-13-5. Authors Sait, N; Aliouane, N; Toukal, L; Hammache, H; Al-Noaimi, M; Helesbeux, JJ; Duval, O in ELSEVIER published article about in [Sait, N.; Aliouane, N.; Hammache, H.] Univ Bejaia, Dept Genie Proc, Lab Electrochim Corros & Valorisat Energet, Bejaia 06000, Algeria; [Toukal, L.] Univ Ferhat Abbas Setif 1, Dept Genie Proc, Lab Electrochim Ingn Mol & Catalyse Redox, Setif, Algeria; [Al-Noaimi, M.] Hashemite Univ, Fac Sci, Dept Chem, POB 330127, Zarqa 13133, Jordan; [Helesbeux, J. J.; Duval, O.] Univ Angers, Univ Bretagne Loire, SFR QUASAV 4207, Lab SONAS,EA921, 42 Rue Georges Morel, Beaucouze, France in 2021, Cited 83. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The inhibition performance of the newly synthesized Ethylene bis [(2-hydroxy-5,1,3-phenylene) bismethylene] tetraphosphonic acid (ETPA) toward carbon steel in 3% NaCl was investigated at different concentrations using potentiodynamic polarization (PDP) and impedance spectroscopy (EIS) methods. It was found that the inhibition capability was increased with increasing inhibitor dose and reach 92% at 10(-3) mol/L. Also, Polarization curves showed that ETPA acts as a mixed type inhibitor with predominantly control of anodic reaction. The new inhibitor was investigated by different spectroscopic methods such as H-1, C-13 and (PNMR)-P-31. The quantum parameters such as absolute electronegativity (chi), energy gap Delta(E) (E-HOMO-E-LUMO), global softness (sigma), global hardness (eta), electrophilicity index (omega) and the number of transfer electrons (Delta N) are calculated by density functional theory (DFT). The experimental also correlated with density functional theory results. The calculations show that ETPA has high density of negative charge located on the oxygen atoms of the phosphonate group facilitating the adsorption of ETPA on the surface of carbon steel. The inhibition efficiency of ETPA was discussed in terms of blocking of electrode surface by adsorption of ETPA molecules through active centers. The adsorption of ETPA on the surface of carbon steel obeyed the Langmuir isotherm paradigm. (C) 2021 Elsevier B.V. All rights reserved.

Welcome to talk about 105-13-5, If you have any questions, you can contact Sait, N; Aliouane, N; Toukal, L; Hammache, H; Al-Noaimi, M; Helesbeux, JJ; Duval, O or send Email.. Product Details of 105-13-5

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Recently I am researching about CYCLOHEXANE OXIDATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; METAL-COMPLEXES; II COMPLEX; SOLVENT; SILICA; DESULFURIZATION, Saw an article supported by the Fundacao para a Ciencia e a Tecnologia (FCT), Portugal (Centro de Quimica Estrutural) [UIDB/00100/2020]; Fundacao para a Ciencia e a Tecnologia (FCT), PortugalPortuguese Foundation for Science and Technology [PTDC/QUI-QIN/29778/2017]; REQUIMTE-LAQV (FCT) [POCI-01-0145-FEDER-007265, UID/QUI/50006/2013]; FCT/MEC [GlyGold PTDC/CTM-CTM/31983/2017]; Fundo Europeu de Desenvolvimento Regional (FEDER) under the PT2020 Partnership Agreement; national funds (OE), through FCT-Fundacao para a Ciencia e a Tecnologia, I.P.. Quality Control of (4-Methoxyphenyl)methanol. Published in ELSEVIER in AMSTERDAM ,Authors: Correia, LMM; Soliman, MMA; Granadeiro, CM; Balula, SS; Martins, LMDRS; Pombeiro, AJL; Alegria, ECBA. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The neutral trichloro[hydrotris(1-pyrazolyl)methane]vanadium(III) [VCl3(Tpm)] (Tpm = HC(pz)(3); pz = pyrazolyl) C-scorpionate complex was immobilized on amine-functionalized mesoporous silica (aptesSBA-15) via an impregnation method forming the [VCl3(Tpm)]@aptesSBA-15 composite. The immobilization of the vanadium compound was confirmed by several characterization techniques, namely SEM/EDS, powder XRD, FT-IR/ATR, ICP and BET surface area analysis, revealing the successful incorporation of the complex, and confirming the structural and morphological preservation of the porous support and the vanadium complex. The vanadium composite was tested as heterogeneous catalyst for the peroxidative oxidation of benzyl alcohol under mild conditions and its catalytic performance was compared to that of the analogous homogeneous [VCl3(Tpm)] complex. The catalytic studies were extended to other substrates. The effect of various parameters, such as amount and type of oxidant, catalyst and additives, temperature and reaction time were investigated allowing to reach overall yields of ca. 60% and turnover numbers (TONs) up to ca. 7.6 x 10(3). The results obtained demonstrated the higher performance of the heterogeneous catalyst using much less [VCl3(Tpm)] complex under a solvent-free system. Furthermore, consecutive reaction cycles could be performed, showing its recycling capacity. Structural stability was also investigated, indicating the viability of the vanadium C-scorpionate composite as catalyst for other oxidative reactions with high industrial interest.

Welcome to talk about 105-13-5, If you have any questions, you can contact Correia, LMM; Soliman, MMA; Granadeiro, CM; Balula, SS; Martins, LMDRS; Pombeiro, AJL; Alegria, ECBA or send Email.. Quality Control of (4-Methoxyphenyl)methanol

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An article Supercritical CO2 extracts from Acacia dealbata flowers WOS:000640418000006 published article about CARBON-DIOXIDE EXTRACTION; FLUID EXTRACTION; ANTIOXIDANT ACTIVITY; CHEMICAL-COMPOSITION; FRACTIONATION; PERFORMANCE; VOLATILES; KINETICS; LUPEOL; LINK in [Casas, Maria P.; Lopez-Hortas, Lucia; Moure, Andres; Dominguez, Herminia] Univ Vigo, Dept Chem Engn, CINBIO, Campus Ourense,Edificio Politen, Orense 32004, Spain; [Diaz-Reinoso, Beatriz] Univ Vigo, CITI, Parque Tecnol Galicia,Rua Galicia 2, Orense 32900, Spain in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: (4-Methoxyphenyl)methanol

Supercritical CO2 was used for the production of extracts from Acacia dealbata flowers. Pressures from 10 to 35 MPa and temperatures from 35? to 55?C were studied to assess their influence on the yield, antiradical properties and composition of the volatiles. The use of ethanol as modifier was also evaluated. Operating at 30 MPa and 45 ?C with 10% ethanol, up to 15% of the ethanol extractables were obtained in 3 h. The selectivity towards alcohol type compounds decreased with time and was enhanced in a sequence of static extraction with pure and ethanol modified CO2 followed by a dynamic stage. The most active fractions showed ABTS radical scavenging activity of 0.22 g Trolox/g extract. Different mathematical models were used to describe the kinetic data. The most abundant compounds in the supercritical extracts were oxygenated triterpenes whereas in conventional ethanolic extracts the main constituents were aliphatic compounds.

Welcome to talk about 105-13-5, If you have any questions, you can contact Casas, MP; Lopez-Hortas, L; Diaz-Reinoso, B; Moure, A; Dominguez, H or send Email.. Recommanded Product: (4-Methoxyphenyl)methanol

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An article Alkylarylation of N-allylbenzamides and N-allylanilines with simple ethers for the direct construction of ether substituted dihydroisoquinolinones and indolines WOS:000510681300006 published article about ONE-POT SYNTHESIS; HOMOPHTHALIC ANHYDRIDE; 3-COMPONENT REACTION; RADICAL CYCLIZATION; TANDEM CATALYSIS; BOND; FUNCTIONALIZATION; BENZAMIDES; ACIDS; HYDROXYALKYLATION in [Li, Yiting; Sun, Song; Cheng, Jiang; Yu, Jin-Tao] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China in 2020, Cited 56. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A radical-initiated cascade addition and cyclization of N-allylbenzamides with simple ethers to construct ether-substituted dihydroisoquinolinones was performed in the presence of CuI. The cleavage of the sp(3) C-H bond in ether and the sp(2) C-H bond in phenyl was involved in this reaction. Moreover, the arylalkylation of N-allylanilines was also realized under similar reaction conditions, providing ether-functionalized indolines in good to moderate yields.

Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Li, YT; Sun, S; Cheng, J; Yu, JT or send Email.

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An article Additive-free aerobic C-H oxidation through a defect-engineered Ce-MOF catalytic system WOS:000660460400006 published article about METAL-ORGANIC FRAMEWORKS; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; HIGHLY EFFICIENT; DRUG-DELIVERY; TOLUENE; ULTRASOUND; PERFORMANCE; AMIDATION; ALCOHOLS in [Karimi, Meghdad; Mohebali, Haleh; Sadeghi, Samira; Mahjoub, Alireza; Heydari, Akbar] Tarbiat Modares Univ, Chem Dept, POB 14155-4838, Tehran, Iran; [Safarifard, Vahid] Iran Univ Sci & Technol, Dept Chem, Tehran 1684613114, Iran in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: (4-Methoxyphenyl)methanol

Ce-UiO-66 MOF, namely cerium-organic framework was prepared through a fast and efficient method under ultrasonic radiation. After preparation, it was identified using some different microscopic and spectroscopic techniques such as PXRD, FT-IR, TG/DTA, BET, BJH, and FE-SEM. The catalytic activity of Ce-UiO-66 MOF was checked in aerobic oxidation of methyl arenas, alcohols and styrene derivatives in a sustainable circumstance with no additives. Moreover, its catalytic activity was surveyed influenced by a number of variables in the ultrasonic synthesis method. Some parameters such as solvent, base, temperature, amount of the catalyst and time were also tested to optimize the aerobic oxidation reaction. After the 10th run, the recycled Ce-MOF showed an acceptable efficiency, which proved its high reusability and stability under optimized conditions. Furthermore, the Ce-UiO-66 was investigated structurally by PXRD method which demonstrated the catalyst stability after the aerobic oxidation reaction.

Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Karimi, M; Mohebali, H; Sadeghi, S; Safarifard, V; Mahjoub, A; Heydari, A or send Email.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts