Month: November 2021

Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Jeong, J; Fujita, K in AMER CHEMICAL SOC published article about in [Jeong, Jaeyoung; Fujita, Ken-ichi] Kyoto Univ, Grad Sch Human & Environm Studies, Kyoto 6068501, Japan in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A new catalytic system for N,N-dimethylamination of primary alcohols using aqueous dimethylamine in the absence of additional organic solvents has been developed. The reaction proceeds via borrowing hydrogen processes, which are atom-efficient and environmentally benign. An iridium catalyst bearing an N-heterocyclic carbene (NHC) ligand exhibited high performance, without showing any deactivation under aqueous conditions. In addition, valuable N,N-dimethylamine derivatives, including biologically active and pharmaceutical molecules, were synthesized. The practical application of this methodology was demonstrated by a gram-scale reaction.

Application In Synthesis of (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Recommanded Product: (4-Methoxyphenyl)methanol. Aarsetoy, R; Ueland, T; Aukrust, P; Michelsen, AE; de la Fuente, RL; Ponitz, V; Brugger-Andersen, T; Grundt, H; Staines, H; Nilsen, DWT in [Aarsetoy, Reidun; Ponitz, Volker; Brugger-Andersen, Trygve; Nilsen, Dennis W. T.] Stavanger Univ Hosp, Dept Cardiol, POB 8100, N-4068 Stavanger, Norway; [Aarsetoy, Reidun; Grundt, Heidi; Nilsen, Dennis W. T.] Univ Bergen, Dept Clin Sci, Bergen, Norway; [Ueland, Thor; Aukrust, Pal; Michelsen, Annika E.] Oslo Univ Hosp, Res Inst Internal Med, Rikshosp, Oslo, Norway; [Aukrust, Pal] Oslo Univ Hosp, Sect Clin Immunol & Infect Dis, Rikshosp, Oslo, Norway; [de la Fuente, Ricardo Leon] Ctr Cardiovasc Salta, Salta, Argentina; [Grundt, Heidi] Stavanger Univ Hosp, Dept Resp Med, Stavanger, Norway; [Staines, Harry] Sigma Stat Serv, Balmullo, Scotland published Angiopoietin-2 and angiopoietin-like 4 protein provide prognostic information in patients with suspected acute coronary syndrome in , Cited 34. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Background Plasma levels of angiopoietin-2 (ANGPT2) and angiopoietin-like 4 protein (ANGPTL4) reflect different pathophysiological aspects of cardiovascular disease. We evaluated their association with outcome in a hospitalized Norwegian patient cohort (n = 871) with suspected acute coronary syndrome (ACS) and validated our results in a similar Argentinean cohort (n = 982). Methods A cox regression model, adjusting for traditional cardiovascular risk factors, was fitted for ANGPT2 and ANGPTL4, respectively, with all-cause mortality and cardiac death within 24 months and all-cause mortality within 60 months as the dependent variables. Results At 24 months follow-up, 138 (15.8%) of the Norwegian and 119 (12.1%) of the Argentinian cohort had died, of which 86 and 66 deaths, respectively, were classified as cardiac. At 60 months, a total of 259 (29.7%) and 173 (17.6%) patients, respectively, had died. ANGPT2 was independently associated with all-cause mortality in both cohorts at 24 months [hazard ratio (HR) 1.27 (95% confidence interval (CI), 1.08-1.50) for Norway, and HR 1.57 (95% CI, 1.27-1.95) for Argentina], with similar results at 60 months [HR 1.19 (95% CI, 1.05-1.35) (Norway), and HR 1.56 (95% CI, 1.30-1.88) (Argentina)], and was also significantly associated with cardiac death [HR 1.51 (95% CI, 1.14-2.00)], in the Argentinean population. ANGPTL4 was significantly associated with all-cause mortality in the Argentinean cohort at 24 months [HR 1.39 (95% CI, 1.15-1.68)] and at 60 months [HR 1.43 (95% CI, 1.23-1.67)], enforcing trends in the Norwegian population. Conclusions ANGPT2 and ANGPTL4 were significantly associated with outcome in similar ACS patient cohorts recruited on two continents. Clinical Trial Registration ClinicalTrials.gov Identifier: NCT00521976. ClinicalTrials.gov Identifier: NCT01377402.

Recommanded Product: (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L in ROYAL SOC CHEMISTRY published article about in [Choudhury, Prabhupada; Behera, Pradyota Kumar; Bisoyi, Tanmayee; Sahu, Santosh Kumar; Sahu, Rashmi Ranjan; Prusty, Smruti Ranjita; Rout, Laxmidhar] Berhampur Univ, Dept Chem, Berhampur 760007, Odisha, India; [Stitgen, Abigail; Scanlon, Joseph] Ripon Coll, Dept Chem, Wisconsin Rapids, WI 54971 USA; [Sahu, Rashmi Ranjan; Kar, Manoranjan] IIT Patna, Dept Phys, Patna, Bihar, India; [Rout, Laxmidhar] Indian Inst Sci Educ & Res, Sch Chem Sci, Berhampur 760007, Odisha, India in 2021, Cited 25. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we report a new protocol for the dehydrogenative oxidation of aryl methanols using the cheap and commercially available catalyst CuSeO3 center dot 2H(2)O. Oxygen-bridged [Cu-O-Se] bimetallic catalysts are not only less expensive than other catalysts used for the dehydrogenative oxidation of aryl alcohols, but they are also effective under mild conditions and at low concentrations. The title reaction proceeds with a variety of aromatic and heteroaromatic methanol examples, obtaining the corresponding carbonyls in high yields. This is the first example using an oxygen-bridged copper-based bimetallic catalyst [Cu-O-Se] for dehydrogenative benzylic oxidation. Computational DFT studies reveal simultaneous H-transfer and Cu-O bond breaking, with a transition-state barrier height of 29.3 kcal mol(-1).

Welcome to talk about 105-13-5, If you have any questions, you can contact Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L or send Email.. Application In Synthesis of (4-Methoxyphenyl)methanol

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Alcohol – Wikipedia,
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In 2021 J ORG CHEM published article about ALLYLATION; ALDEHYDES in [Botubol-Ares, Jose Manuel; Jesus Duran-Pena, Maria] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Campus Univ Rio San Pedro S-N,4a Planta, Cadiz 11510, Spain; [Chahboun, Rachid; Jimenez, Fermin; Alvarez-Manzaneda, Enrique] Univ Granada, Fac Ciencias, Inst Biotecnol, Dept Quim Organ, Granada 18071, Spain; [Alvarez-Manzaneda, Ramon] Univ Almeria, Dept Quim & Fis, Area Quim Organ, Almeria 04120, Spain in 2021, Cited 37. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

A general and efficient method for the deconjugative alpha-alkylation of alpha,beta-unsaturated aldehydes promoted by a synergistic effect between (BuOK)-Bu-t and NaH, which considerably increases the reaction rate under mild conditions, is reported. The beta,gamma-unsaturated aldehyde, resulting from the alpha-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids.

Welcome to talk about 105-13-5, If you have any questions, you can contact Chahboun, R; Botubol-Ares, JM; Duran-Pena, MJ; Jimenez, F; Alvarez-Manzaneda, R; Alvarez-Manzaneda, E or send Email.. Safety of (4-Methoxyphenyl)methanol

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Alcohol – Wikipedia,
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In 2021 APPL ORGANOMET CHEM published article about NONREDOX METAL-IONS; SELECTIVE OXIDATION; AEROBIC OXIDATION; DIOXYGEN ACTIVATION; PD NANOPARTICLES; OXYGEN; HECK; COMPLEXES; FRONTIER; LIGAND in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

Category: alcohols-buliding-blocks. Welcome to talk about 105-13-5, If you have any questions, you can contact Zeng, M; Lou, CL; Xue, JW; Jiang, HW; Li, KW; Chen, ZQ; Fu, ST; Yin, GC or send Email.

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Alcohol – Wikipedia,
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Authors Lan, XB; Ye, ZR; Yang, CH; Li, WK; Liu, JH; Huang, M; Liu, Y; Ke, ZF in WILEY-V C H VERLAG GMBH published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.

Welcome to talk about 105-13-5, If you have any questions, you can contact Lan, XB; Ye, ZR; Yang, CH; Li, WK; Liu, JH; Huang, M; Liu, Y; Ke, ZF or send Email.. Computed Properties of C8H10O2

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Computed Properties of C8H10O2. Authors Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA in WILEY-V C H VERLAG GMBH published article about in [Ruiz-Castaneda, Margarita; Santos, Lucia; Manzano, Blanca R.; Jalon, Felix A.] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim IRICA, Avda CJ Cela 10, Ciudad Real 13071, Spain; [Espino, Gustavo] Univ Burgos, Fac Ciencias, Dept Quim, Plaza Misael Banuelos S-N, Burgos 09001, Spain in 2021, Cited 107. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Deuterium labeling is an interesting process that leads to compounds of use in different fields. We describe the transfer hydrogenation of aldehydes and the selective C-1 deuteration of the obtained alcohols in D2O, as the only deuterium source. Different aromatic, alkylic and alpha,beta-unsaturated aldehydes were reduced in the presence of [RuCl(p-cymene)(dmbpy)]BF4, (dmbpy=4,4 ‘-dimethyl-2,2 ‘-bipyridine) as the pre-catalyst and HCO2Na/HCO2H as the hydrogen source. Moreover, furfural and glucose, were selectively reduced to the valuable alcohols, furfuryl alcohol and sorbitol. The processes were carried out in neat water or in a biphasic water/toluene system. The biphasic system allowed easy recycling, higher yields, and higher selective D incorporation (using D2O/toluene). The deuteration took place due to an efficient effective M-H/D+ exchange from D2O that allows the inversion of polarity of D+ (umpolung). DFT calculations that explain the catalytic behavior in water are also included.

Welcome to talk about 105-13-5, If you have any questions, you can contact Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA or send Email.. Computed Properties of C8H10O2

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Authors Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L in ROYAL SOC CHEMISTRY published article about in [Choudhury, Prabhupada; Behera, Pradyota Kumar; Bisoyi, Tanmayee; Sahu, Santosh Kumar; Sahu, Rashmi Ranjan; Prusty, Smruti Ranjita; Rout, Laxmidhar] Berhampur Univ, Dept Chem, Berhampur 760007, Odisha, India; [Stitgen, Abigail; Scanlon, Joseph] Ripon Coll, Dept Chem, Wisconsin Rapids, WI 54971 USA; [Sahu, Rashmi Ranjan; Kar, Manoranjan] IIT Patna, Dept Phys, Patna, Bihar, India; [Rout, Laxmidhar] Indian Inst Sci Educ & Res, Sch Chem Sci, Berhampur 760007, Odisha, India in 2021, Cited 25. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we report a new protocol for the dehydrogenative oxidation of aryl methanols using the cheap and commercially available catalyst CuSeO3 center dot 2H(2)O. Oxygen-bridged [Cu-O-Se] bimetallic catalysts are not only less expensive than other catalysts used for the dehydrogenative oxidation of aryl alcohols, but they are also effective under mild conditions and at low concentrations. The title reaction proceeds with a variety of aromatic and heteroaromatic methanol examples, obtaining the corresponding carbonyls in high yields. This is the first example using an oxygen-bridged copper-based bimetallic catalyst [Cu-O-Se] for dehydrogenative benzylic oxidation. Computational DFT studies reveal simultaneous H-transfer and Cu-O bond breaking, with a transition-state barrier height of 29.3 kcal mol(-1).

Welcome to talk about 105-13-5, If you have any questions, you can contact Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L or send Email.. Category: alcohols-buliding-blocks

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

Recommanded Product: 105-13-5. Authors Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM in ROYAL SOC CHEMISTRY published article about in [Xiao, Wanlong; Mo, Yuhao; Guo, Jing; Su, Zhishan; Dong, Shunxi; Feng, Xiaoming] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China in 2021, Cited 64. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

New types of C-2-symmetric chiral macrodiolides are readily obtained via chiral N,N ‘-dioxide-scandium(iii) complex-promoted asymmetric tandem Friedel-Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles. This protocol provides an array of enantioenriched macrodiolides with 16, 18 or 20-membered rings in moderate to good yields with high diastereoselectivities and excellent enantioselectivities through adjusting the length of the tether at the C3 position of indoles. Density functional theory calculations indicate that the formation of macrocycles is more favorable than that of 9-membered-ring lactones in terms of kinetics and thermodynamics. The potential utility of these intriguing chiral macrodiolide molecules is demonstrated in the enantiomeric recognition of aminols and chemical recognition of metal ions.

Recommanded Product: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Xiao, WL; Mo, YH; Guo, J; Su, ZS; Dong, SX; Feng, XM or send Email.

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts

An article Palladium (II)-catalyzed homogeneous alcohol oxidations: Disclosing the crucial contribution of palladium nanoparticles in catalysis WOS:000590610700001 published article about NONREDOX METAL-IONS; SELECTIVE OXIDATION; AEROBIC OXIDATION; DIOXYGEN ACTIVATION; PD NANOPARTICLES; OXYGEN; HECK; COMPLEXES; FRONTIER; LIGAND in [Zeng, Miao; Lou, Chenlin; Xue, Jing-Wen; Jiang, Hongwu; Li, Kaiwen; Chen, Zhuqi; Fu, Shitao; Yin, Guochuan] Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China in 2021, Cited 35. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Versatile redox catalysts play the significant roles in alcohol oxidations, in which the mechanisms for homogeneous and heterogeneous alcohol oxidations are generally different. This work introduced a Lewis acid (LA) promoted homogeneous alcohol oxidation with Pd (OAc)(2) catalyst by using oxygen balloon as the oxidant source. It was found that adding Lewis acid such as Sc (OTf)(3) significantly accelerated Pd (II)-catalyzed alcohol oxidations; notably, the time courses of oxidations monitored by GC and H-1 NMR disclosed that there existed two processes including the initial sluggish oxidation followed by a rapid oxidation. The promotional effect of Lewis acid was attributed to the formation of heterobimetallic Pd (II)/LA species, which improved the oxidizing power of the palladium (II) species, thus accelerating alcohol oxidation in the induction period. Correlating the sizes of in situ generated palladium nanoparticles with the time course of alcohol oxidation further disclosed that the loosely, spherically large nanoparticles, which were composed of many tiny nanoparticles having the size less than 10 nm, were responsible for the rapid oxidation, whereas those highly dispersed, tiny nanoparticles having the size less than 10 nm were not responsible for the rapid oxidation.

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: (4-Methoxyphenyl)methanol

Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts