Month: November 2021

Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Xia, YY; Lv, QY; Yuan, H; Wang, JY in SPRINGER INTERNATIONAL PUBLISHING AG published article about in [Xia, Yu-Yan; Lv, Qing-Yang; Yuan, Hua; Wang, Jia-Yi] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430073, Peoples R China in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

An efficient method for catalyzing the ammoxidation of aromatic alcohols to aromatic nitriles was developed, in which a new heterogeneous catalyst based on transition metal elements was employed, the new catalyst was named Co-[Bmim]Br/C-700 and then characterized by X-ray photo-electronic spectroscopy, transmission electron microscope and X-ray diffraction. The reaction was carried out by two consecutive dehydrogenations under the catalysis of Co-[Bmim]Br/C-700, which catalytically oxidized the alcohol to the aldehyde, and then the aldehyde was subjected to ammoxidation to the nitrile. The catalyst system was suitable for a wide range of substrates and nitriles obtained in high yields, especially, the conversion rate of benzyl alcohol, 4-methoxybenzyl alcohol, 4-chlorobenzyl alcohol and 4-nitrobenzyl alcohol reached 100%. The substitution of ammonia and oxygen for toxic cyanide to participate in the reaction accords with the theory of green chemistry.

Welcome to talk about 105-13-5, If you have any questions, you can contact Xia, YY; Lv, QY; Yuan, H; Wang, JY or send Email.. Application In Synthesis of (4-Methoxyphenyl)methanol

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SDS of cas: 105-13-5. Malatinec, S; Bednarova, E; Tanaka, H; Kotora, M in [Malatinec, Stefan; Bednarova, Eva; Tanaka, Hiroki; Kotora, Martin] Charles Univ Prague, Fac Sci, Dept Organ Chem, Chem, Albertov 6, Prague 12843 2, Czech Republic; [Tanaka, Hiroki] Okayama Univ, Res Inst Interdisciplinary Sci, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan published Highly Enantioselective Ring-Opening of meso-Epoxides with O- and N-Nucleophiles Catalyzed by a Chiral Sc(III)/bipyridine Complex in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The ring-opening of epoxides is a synthetically significant process widely applied in all kinds of chemistry. Herein, we report the catalytic and highly enantioselective variant of this reaction exploiting our recent endeavors to design and synthesize chiral bipyridine type ligands. A Sc-complex with a newly developed bipyridine ligand exhibited high reactivity and stereocontrol in the desymmetrization of meso-epoxides with various alcohols. The respective enantiomerically enriched 1,2-alkoxyalcohols were obtained with e.r. values of up to 99.5:0.5 for various alcohols regardless of their nature (benzyl, alkyl, cycloalkyl, allyl, propargyl, etc.). We attempted ring-opening of meso-epoxides with anilines as well; however, it proceeded with lower enantioselectivity and was strongly depended on the electronic effect of substituents attached to the aromatic ring.

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An article Role of dietary carbohydrates on risk of lung cancer WOS:000644431300012 published article about GROWTH-FACTOR-I; GLYCEMIC LOAD; SCREENING TRIAL; MEAT MUTAGENS; HEME IRON; PROSTATE; INDEX; INSULIN; VALUES; FIBER in [Tao, Jun; Lam, Wendy W. T.; Pang, Herbert] Univ Hong Kong, Li Ka Shing Fac Med, Sch Publ Hlth, Hong Kong, Peoples R China; [Jatoi, Aminah] Mayo Clin, Dept Oncol, Rochester, MN USA; [Crawford, Jeffrey] Duke Univ, Med Ctr, Duke Canc Inst, Durham, NC USA; [Ho, James C.] Univ Hong Kong, Li Ka Shing Fac Med, Dept Med, Hong Kong, Peoples R China; [Wang, Xiaofei; Pang, Herbert] Duke Univ, Sch Med, Dept Biostat & Bioinformat, Durham, NC USA; [Lam, Wendy W. T.] Univ Hong Kong, Jockey Club Inst Canc Care, Hong Kong, Peoples R China in 2021, Cited 53. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Objectives: Inconsistent findings have been reported on the link between dietary carbohydrates and lung cancer. This study aims to comprehensively evaluate the role of dietary carbohydrates on lung cancer risk. Materials and methods: The prospective study is based on the PLCO trial, which recruited 113,096 eligible participants across the United States. Participants had to have completed baseline and diet history questionnaires. The incidence of lung cancer was acquired through self-report and medical record follow-up. A multivariable logistic model adjusted for confounders was used to estimate odds ratios (ORs) and 95 % confidence intervals (CIs) of dietary carbohydrates, fiber, whole grains, glycemic index (GI) and glycemic load (GL) for lung cancer. Similar methods were applied in analyzing the carbohydrates and fiber from different food sources. Multinomial logistic models were used for sensitivity analysis with lung cancer subtypes as outcomes. Results: Dietary carbohydrates and GL were inversely associated with lung cancer incidence in the PLCO population. Among various carbohydrates, 30-g daily consumption of dietary fiber was related to a lower risk of lung cancer (fourth vs first quartile OR: 0.62, 95 % CI: 0.54-0.72) compared with 8.8-g. Furthermore, consuming whole grains 2.3 servings per day as opposed to 0.3 servings per day was associated with a lower risk of lung cancer (OR: 0.73, 95 % CI: 0.64-0.83). A higher risk of lung cancer was seen for the consumption of high-GI food (OR: 1.19, 95 % CI: 1.05?1.35) and refined carbohydrates from soft drinks (OR: 1.23, 95 % CI: 1.04?1.46). Conclusion: Carbohydrates and fiber from fruits, vegetables and whole grains are associated with lower lung cancer risk. Refined carbohydrates from processed food, such as soft drinks, appear to increase risk.

COA of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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I found the field of Chemistry very interesting. Saw the article OH/Na co-functionalized carbon nitride: directional charge transfer and enhanced photocatalytic oxidation ability published in 2020. Recommanded Product: 105-13-5, Reprint Addresses Sun, YJ (corresponding author), Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing Key Lab Catalysis & New Environm Mat, Chongqing 400067, Peoples R China.; Sun, YJ (corresponding author), Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Res Ctr Environm Sci & Technol, Chengdu 611731, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Graphitic carbon nitride (g-C3N4, CN for short) is a compelling visible-light responsive photocatalyst. However, its photocatalytic efficiency is low due to the random carrier transfer in planes and insufficient redox potential. Herein, we build oxygen functional group modified sodium-doped carbon nitride (OH/Na co-functionalized carbon nitride) to promote directional transfer of charge carriers for acceleration of separation and enhance redox potential for efficient oxidation of NO in air. Specifically, the function of sodium atoms could control the directional transfer of random carriers from the intralayer to the oxygen functional group-modified surface for the purpose of effectively reducing photogenerated electron-hole recombination. Meanwhile, the modification by oxygen-containing functional groups could adjust the band structure of CN, thereby increasing the oxidation-reduction potential of NO in the photocatalyst. The transformation pathways and reaction mechanism of photocatalytic NO oxidation on CN and OH/Na co-functionalized carbon nitride have also been explicated by ESR spectroscopy and in situ DRIFTS and compared. This work provides a new method for simultaneously controlling the random transfer of carriers and adjusting the energy band structure of CN to optimize its photocatalytic efficiency. It is also possible to extend this strategy to improve the performance of other 2D layered catalysts for photocatalytic oxidation.

Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, JD; Cui, W; Chen, RM; He, Y; Yuan, CW; Sheng, JP; Li, JY; Zhan, YX; Dong, F; Sun, YJ or send Email.. Recommanded Product: 105-13-5

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Epifanov, M; Mo, JY; Dubois, R; Yu, H; Sammis, GM in AMER CHEMICAL SOC published article about in [Epifanov, Maxim; Mo, Jia Yi; Dubois, Rudy; Yu, Hao; Sammis, Glenn M.] Univ British Columbia, Dept Chem, Columbia, BC V6T 1Z1, Canada in 2021, Cited 48. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

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Computed Properties of C8H10O2. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

Computed Properties of C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF or send Email.

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In 2021 POLYHEDRON published article about ONE-POT SYNTHESIS; SELECTIVE ALKYLATION; EFFICIENT; COMPLEX; ANILINES; SUBSTITUTION; OXIDATION; AMIDES in [Feng, Xinshu; Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Guangzhou 510006, Peoples R China in 2021, Cited 40. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

A series of air-stable N-heterocyclic carbene (NHC) Ir(III) complexes (Ir1-6), bearing various combinations of chlorine, pyridine and NHC ligands, were assayed for the N-alkylation of amines with alcohols. It was found that Ir3, with two monodentate 1,3-bis-methyl-imidazolylidene (IMe) ligands, emerged as the most active complex. A large variety of amines and primary alcohols were efficiently converted into mono-N-alkylated amines in 53-96% yields. As a special highlight, for the challenging MeOH, selective N-monomethylation could be achieved using KOH as a base under an air atmosphere. Moreover, this catalytic system was successfully applied to the gram-scale synthesis of some valuable compounds. (C) 2021 Elsevier Ltd. All rights reserved.

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In 2021 APPL ORGANOMET CHEM published article about ONE-POT SYNTHESIS; HETEROCYCLIZATION SYNTHESIS; NITROGEN-HETEROCYCLES; 3-COMPONENT SYNTHESIS; PURINE DERIVATIVES; AEROBIC OXIDATION; EFFICIENT; ALCOHOLS; ALDEHYDES; 1,3,5-TRIAZINES in [Debnath, Pradip] Maharaja Bir Bikram Coll, Dept Chem, Agartala 799004, Tripura, India; [Sahu, Gouranga] Ramkrishna Mahavidyalaya, Dept Chem, Unakoti, India; [De, Utpal C.] Tripura Univ, Dept Chem, Agartala, India in 2021, Cited 96. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Name: (4-Methoxyphenyl)methanol

A dehydrogenative coupling of N-uracil amidines with (hetero)aryl methanols has been developed, allowing for the facile synthesis of a broad range of structurally diverse pyrimidouracils. By applying [RuCl2(p-cymene)](2)/Cs2CO3 as an efficient catalytic system, the easily available, cheap (hetero)aryl methanols were firstly employed for oxidative insertion/C-H amination into the N-uracil amidines, providing highly functionalized pyrimido[4,5-d]pyrimidine-2,4-diones. Due to the better stability of alcohols than aldehydes, this synthetic protocol is applicable to a broad range of alcoholic substrates and does not required any protection during the whole preparation process. The presented protocol has the potential to prepare valuable products which cannot be accessed presently or extremely arduous to procure by following regular procedure. Hence, this is a remarkably improved protocol compared with the existing methodologies. The overall reaction sequence is an effective oxidation-imination-cyclization tandem process catalyzed by ruthenium catalyst.

Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.. Name: (4-Methoxyphenyl)methanol

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HPLC of Formula: C8H10O2. Recently I am researching about DIELS-ALDER REACTION; HYDROXY-O-QUINODIMETHANES; PHOTOASSISTED SYNTHESIS; ABSOLUTE STEREOCHEMISTRY; NATURAL-PRODUCT; ANALOGS THEREOF; SILYL ETHERS; XESTOQUINONE; SPONGE; HALENAQUINONE, Saw an article supported by the . Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Lu, XL; Qiu, YY; Yang, BC; He, HB; Gao, SH. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6-7 steps using an easily accessible meso-cyclohexadienone derivative. The [6,6]-bicyclic decalin B-C ring and the all-carbon quaternary stereocenter at C-6 were prepared via a desymmetric intramolecular Michael reaction with up to 97% ee. The naphthalene diol D-E ring was constructed through a sequence of Ti(Oi-Pr)(4)-promoted photoenolization/Diels-Alder, dehydration, and aromatization reactions. This asymmetric strategy provides a scalable route to prepare target molecules and their derivatives for further biological studies.

HPLC of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Lu, XL; Qiu, YY; Yang, BC; He, HB; Gao, SH or send Email.

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Authors Tian, YW; Guo, XQ; Li, MC; Li, CM; Hu, XQ; Jin, LQ; Sun, N; Hu, BX; Shen, ZL in AMER CHEMICAL SOC published article about AEROBIC OXIDATION; SILICA; EPOXIDATION; TEMPO in [Tian, Yangwu; Guo, Xiaqun; Li, Meichao; Li, Chunmei; Hu, Xinquan; Jin, Liqun; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China; [Li, Chunmei] Shaoxing Univ, Sch Chem & Chem Engn, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China in 2021, Cited 38. Recommanded Product: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein, we designed and synthesized an SBA-15 supported 1-methyl-2-azaadamanane N-oxyl (1-Me-AZADO) and investigated its catalytic performance for selective oxidation of alcohols under Anelli’s conditions. The first example of immobilization of 1-Me-AZADO was very important to advance the oxgenation effectively because this supported N-oxyl has excellent catalytic activity for oxidation of alcohols to carbonyl compounds, and more importantly, it can be conveniently recovered and reused at least 6 times without significant effect on its catalytic efficiency.

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