COA of Formula: C8H10O2. Wu, D; Bu, QQ; Guo, C; Dai, B; Liu, N in [Wu, Di; Bu, Qingqing; Dai, Bin; Liu, Ning] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China; [Guo, Cheng] Zhejiang Univ, Affiliated Hosp 2, Sch Med, Canc Inst, Hangzhou 310009, Zhejiang, Peoples R China published Cooperative catalysis of molybdenum with organocatalysts for distribution of products between amines and imines in 2021, Cited 73. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.
Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts