An article Iron-Catalyzed Hydrogen Transfer Reduction of Nitroarenes with Alcohols: Synthesis of Imines and Aza Heterocycles WOS:000606840200084 published article about ONE-POT SYNTHESIS; BORROWING HYDROGEN; 2-SUBSTITUTED BENZIMIDAZOLES; TRANSITION-METAL; N-ALKYLATION; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; QUINOXALINE DERIVATIVES; SWITCHABLE SYNTHESIS; AROMATIC DIAMINES in [Wu, Jiajun; Darcel, Christophe] Univ Rennes, CNRS ISCR, Inst Sci Chim Rennes, UMR 6226, F-35000 Rennes, France in 2021, Cited 137. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Name: (4-Methoxyphenyl)methanol
A straightforward and selective reduction of nitroarenes with various alcohols was efficiently developed using an iron catalyst via a hydrogen transfer methodology. This protocol led specifically to imines in 30-91% yields, with a good functional group tolerance. Noticeably, starting from o-nitroaniline derivatives, in the presence of alcohols, benzimidazoles can be obtained in 64-72% yields when the reaction was performed with an additional oxidant, DDQ, and quinoxalines were prepared from 1,2-diols in 28-96% yields. This methodology, unprecedented at iron for imines, also provides a sustainable alternative for the preparation of quinoxalines and benzimidazoles.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts