Recently I am researching about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; SOLID NANOPARTICLES; CATALYZED REACTIONS; PHASE INVERSION; EMULSIONS; PARTICLES; INTERFACE; CLUSTERS; SIZE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21771081]; Changbai Mountain Scholars Program [440020031182]; Provincial Major Project [20180101001JC]; PetroChina Scientific Research and Technology Development Project [2018A-0907]. Recommanded Product: (4-Methoxyphenyl)methanol. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
Organic reactors in a green solvent (water) is the goal of sustainable development. Green nanoreactors with excellent amphiphilicity and catalytic activity are strongly desired. Herein, a novel amphiphilic nanoreactor Pd@amZSM-5 with ultrasmall size has been successfully synthesized via a simple one-step oil bath method, subjected to the modification-etching-modification strategy and in situ reduction of Pd2+. Ultrasmall Pd@amZSM-5 nanoreactors (60 nm) with hierarchical structures showed outstanding amphiphilicity for forming Pickering emulsions with fine uniform droplets (50 mu m). Fine droplets formed short diffusion distances, which can significantly improve the catalytic activity in biphasic reactions. Moroever, the ultrasmall Pd@amZSM-5 nanoreactors demonstrated excellent catalytic activity for the selective oxidation of alcohols in water using air as the oxidant. Alkali was not present in the reaction system. The hydrophilic aminopropyl groups on the surface of the Pd@amZSM-5 nanoreactors not only changed the affinity of the zeolite surface and provided targeting points for Pd nanoparticles but also provided an alkaline environment for the selective oxidation of alcohols. The ultrasmall Pd@amZSM-5 nanoreactors presented excellent universality for aromatic alcohols (with >90% conversion and >90% selectivity) and allylic alcohols (with 100% conversion and 100% selectivity).
Recommanded Product: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT or concate me.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts