Month: October 2021

Ou, W; Xiang, XD; Zou, R; Xu, Q; Loh, KP; Su, CL in [Ou, Wei; Xiang, Xudong; Zou, Ru; Su, Chenliang] Shenzhen Univ, Int Collaborat Lab 2D Mat Optoelect Sci & Technol, Engn Technol Res Ctr 2D Mat Informat Funct Device, Inst Microscale Optoelect, Shenzhen 518060, Peoples R China; [Xu, Qing] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Zhejiang, Peoples R China; [Loh, Kian Ping] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore published Room-Temperature Palladium-Catalyzed Deuterogenolysis of Carbon Oxygen Bonds towards Deuterated Pharmaceuticals in 2021, Cited 50. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Site-specific incorporation of deuterium into drug molecules to study and improve their biological properties is crucial for drug discovery and development. Herein, we describe a palladium-catalyzed room-temperature deuterogenolysis of carbon-oxygen bonds in alcohols and ketones with D-2 balloon for practical synthesis of deuterated pharmaceuticals and chemicals with benzyl-site (sp(3) C-H) D-incorporation. The highlights of this deoxygenative deuteration strategy are mild conditions, broad scope, practicability and high chemoselectivity. To enable the direct use of D2O, electrocatalytic D2O-splitting is adapted to in situ supply D-2 on demand. With this system, the precise incorporation of deuterium in the metabolic position (benzyl-site) of ibuprofen is demonstrated in a sustainable and practical way with D2O.

COA of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Ou, W; Xiang, XD; Zou, R; Xu, Q; Loh, KP; Su, CL or concate me.

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Category: alcohols-buliding-blocks. Recently I am researching about BIS(IMINO)PYRIDINE COBALT COMPLEXES; CHEMOSELECTIVE HYDROGENATION; IRON; EFFICIENT; SOLVENT; AMIDES; MILD; HYDROBORATION; ISOMERIZATION; INHIBITION, Saw an article supported by the CSIR, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]; MHRD; DST/INSPIRE fellowship [IF160793]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Base-metal catalysts Co1, Co2 and Co3 were synthesized from designed pincer ligands L-1, L-2 and L-3 having NNN donor atoms respectively. Co1, Co2 and Co3 were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures of Co1 and Co3. Catalysts Col, Co2 and Co3 were utilized to study the dehydrogenative activation of alcohols for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.

Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K or concate me.

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SDS of cas: 105-13-5. Authors Jeong, J; Fujita, K in AMER CHEMICAL SOC published article about in [Jeong, Jaeyoung; Fujita, Ken-ichi] Kyoto Univ, Grad Sch Human & Environm Studies, Kyoto 6068501, Japan in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A new catalytic system for N,N-dimethylamination of primary alcohols using aqueous dimethylamine in the absence of additional organic solvents has been developed. The reaction proceeds via borrowing hydrogen processes, which are atom-efficient and environmentally benign. An iridium catalyst bearing an N-heterocyclic carbene (NHC) ligand exhibited high performance, without showing any deactivation under aqueous conditions. In addition, valuable N,N-dimethylamine derivatives, including biologically active and pharmaceutical molecules, were synthesized. The practical application of this methodology was demonstrated by a gram-scale reaction.

SDS of cas: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Jeong, J; Fujita, K or concate me.

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In 2021 APPL ORGANOMET CHEM published article about ONE-POT SYNTHESIS; HETEROCYCLIZATION SYNTHESIS; NITROGEN-HETEROCYCLES; 3-COMPONENT SYNTHESIS; PURINE DERIVATIVES; AEROBIC OXIDATION; EFFICIENT; ALCOHOLS; ALDEHYDES; 1,3,5-TRIAZINES in [Debnath, Pradip] Maharaja Bir Bikram Coll, Dept Chem, Agartala 799004, Tripura, India; [Sahu, Gouranga] Ramkrishna Mahavidyalaya, Dept Chem, Unakoti, India; [De, Utpal C.] Tripura Univ, Dept Chem, Agartala, India in 2021, Cited 96. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Safety of (4-Methoxyphenyl)methanol

A dehydrogenative coupling of N-uracil amidines with (hetero)aryl methanols has been developed, allowing for the facile synthesis of a broad range of structurally diverse pyrimidouracils. By applying [RuCl2(p-cymene)](2)/Cs2CO3 as an efficient catalytic system, the easily available, cheap (hetero)aryl methanols were firstly employed for oxidative insertion/C-H amination into the N-uracil amidines, providing highly functionalized pyrimido[4,5-d]pyrimidine-2,4-diones. Due to the better stability of alcohols than aldehydes, this synthetic protocol is applicable to a broad range of alcoholic substrates and does not required any protection during the whole preparation process. The presented protocol has the potential to prepare valuable products which cannot be accessed presently or extremely arduous to procure by following regular procedure. Hence, this is a remarkably improved protocol compared with the existing methodologies. The overall reaction sequence is an effective oxidation-imination-cyclization tandem process catalyzed by ruthenium catalyst.

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Computed Properties of C8H10O2. Authors Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K in AMER CHEMICAL SOC published article about in [Yamamoto, Yuki; Ota, Miyuto; Kodama, Shintaro; Michimoto, Kazuki; Nomoto, Akihiro; Ogawa, Akiya] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan; [Furuya, Mitsunori; Kawakami, Kiminori] Mitsubishi Chem Corp, Sci & Innovat Ctr, Yokohama, Kanagawa 2278502, Japan in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A green method for the oxidation of alcohols to carboxylic acids was developed using a novel co-catalytic system based on gold, silver, and copper catalysts. This reaction system was conducted under atmospheric oxygen in water and mild conditions to selectively oxidize 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, as a building block for polyethylene furanoate, which is a 100% bio-based, future alternative to the petroleum-based polyethylene terephthalate. Furthermore, various primary alcohols were conveniently oxidized to their corresponding carboxylic acids in up to quantitative yields.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Yamamoto, Y; Ota, M; Kodama, S; Michimoto, K; Nomoto, A; Ogawa, A; Furuya, M; Kawakami, K or concate me.

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An article Fe Doped MIL-101/Graphene Nanohybrid for Photocatalytic Oxidation of Alcohols Under Visible-Light Irradiation WOS:000604191700004 published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; AROMATIC ALCOHOLS; HYDROGEN-PRODUCTION; REACTIVE DYE; NANOCOMPOSITE; EFFICIENT; MIL-101; NANOPARTICLES; PERFORMANCE in [Wang, Mingming; Ma, Yali; Lv, Bolin; Hua, Fenglin; Meng, Shuangyan; Lei, Xuedi; Wang, Qingtao; Su, Bitao; Lei, Ziqiang; Yang, Zhiwang] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Key Lab Ecofunct Polymer Mat,Minist Educ, Lanzhou 730070, Peoples R China in 2021, Cited 44. Name: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A novel photoactive porous material of GR/FeMIL-101 based on FeMIL-101 metal organic frameworks (MOFs) was successfully synthesized via a simple hydrothermal method. The structural and photoelectric properties of the GR/FeMIL-101 was analyzed by XRD, SEM, TEM, TGA, XPS, UV-vis DRS, FT-IR, PL and EIS methods. The photocatalytic performance for the selective oxidation of benzyl alcohol with GR/FeMIL-101 as catalysts was evaluated under visible light irradiation. The results showed that the GR/FeMIL-101 nanohybrid had better photocatalytic performance than both of FeMIL-101 and the pristine MIL-101. It was further found that the incorporation of Fe and MIL-101 caused valence fluctuations of Fe3+/Fe2+ which improved the absorption of visible-light and increased the separation efficiency of photogenerated charges. In addition, the combination of FeMIL-101 and GR could further promote the transfer rate of the photoelectrons. The mechanism of the reaction revealed that center dot O-2(-) was the dominating active specie in this reaction through active species trapping experiments. [GRAPHICS] .

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wang, MM; Ma, YL; Lv, BL; Hua, FL; Meng, SY; Lei, XD; Wang, QT; Su, BT; Lei, ZQ; Yang, ZW or concate me.. Name: (4-Methoxyphenyl)methanol

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Authors Wang, ZH; Wang, H; Wang, H; Li, L; Zhou, MD in AMER CHEMICAL SOC published article about in [Wang, Zhao-Hui; Wang, He; Wang, Hua; Li, Lei; Zhou, Ming-Dong] Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China in 2021, Cited 63. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

In this work, ruthenium(II)-catalyzed C-C/C-N annulation of 2-arylquinazolinones with vinylene carbonate is reported to synthesize fused quinazolinones. This catalytic system tolerates a wide range of substrates with excellent functional-group compatibility. In this transformation, the vinylene carbonate acts as an ethynol surrogate without any external oxidant involved. Furthermore, preliminary mechanistic studies were conducted, and a plausible catalytic cycle was also proposed.

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An article Dinuclear Copper(II) Complexes with N,O Donor Ligands: Partial Ligand Hydrolysis and Alcohol Oxidation Catalysis WOS:000651570800001 published article about SCHIFF-BASE COMPLEXES; AEROBIC OXIDATION; METAL-COMPLEXES; COORDINATION POLYMERS; CU-II; PEROXIDATIVE OXIDATION; DICOPPER(II) COMPLEX; SELECTIVE OXIDATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES in [Barma, Arpita; Bhattacharjee, Aradhita; Roy, Partha] Jadavpur Univ, Dept Chem, Kolkata 700032, India in 2021, Cited 115. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: (4-Methoxyphenyl)methanol

Two copper(II) complexes [Cu-2(L-1)(2)] (1) and [Cu-2(L-2)(2)] (2) where H2L1=2-hydroxy-3-((3-hydroxy-2,2-dimethylpropylimino)methyl)-5-methylbenzaldehyde and H2L2=2-hydroxy-3-(((1-hydroxypropan-2-yl)imino)methyl)-5-methylbenzaldehyde have been synthesized and used as catalysts in alcohol oxidation. 2,6-Diformyl-4-methylphenol (DFP) based Schiff-base ligands, 3,3 ‘-(2-hydroxy-5-methyl-1,3-phenylene)bis(methan-1-yl-1-ylidene)bis(azan-1-yl-1-ylidene)bis(2,2-dimethylpropan-1-ol) (H3L ‘) and 2,2 ‘-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methanylylidene))bis(azanylylidene))bis(propan-1-ol) (H3L ”), undergo partial hydrolysis to convert one of the azomethine groups to aldehyde group to give H2L1 and H2L2, and then react with copper(II) acetate to yield complex 1 and 2, respectively. These complexes have been characterized by standard methods such as elemental analysis, room temperature magnetic studies, FT-IR, UV-vis, ESI-mass spectral analyses, cyclic voltammogram, etc. The structures of dinuclear complexes with modified ligands have been confirmed by single crystal X-ray diffraction analysis. Complex 1 and 2 have been used as catalysts for the oxidation of benzyl alcohol, 4-methyl benzyl alcohol, 4-methoxy benzyl alcohol, 4-nitro benzyl alcohol and 4-bromo benzyl alcohol to the corresponding aldehyde as the sole product. Efficiency of the catalyst depends on the chain length and substitution on the chain of the ligand.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Barma, A; Bhattacharjee, A; Roy, P or concate me.. Recommanded Product: (4-Methoxyphenyl)methanol

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Recommanded Product: 105-13-5. Authors Luo, NH; Zhong, YH; Wen, HL; Shui, HL; Luo, RS in WILEY-V C H VERLAG GMBH published article about in [Luo, Nianhua; Zhong, Yuhong; Wen, Huiling; Shui, Hongling; Luo, Renshi] Gannan Med Univ, Sch Pharmaceut Sci, Ganzhou 341000, Jiangxi, Peoples R China in 2021, Cited 94. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Ketones are of great importance in synthesis, biology, and pharmaceuticals. This paper reports an iridium complexes-catalyzed cross-coupling of alcohols via hydrogen borrowing, affording a series of alpha-alkylated ketones in high yield (86 %-95 %) and chemoselectivities (>99 : 1). This methodology has the advantages of low catalyst loading (0.1 mol%) and environmentally benign water as the solvent. Studies have shown the amount of base has a great impact on chemoselectivities. Meanwhile, deuteration experiments show water plays an important role in accelerating the reduction of the unsaturated ketones intermediates. Remarkably, a gram-scale experiment demonstrates this methodology of iridium-catalyzed cross-coupling of alcohols has potential application in the practical synthesis of alpha-alkylated ketones.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Luo, NH; Zhong, YH; Wen, HL; Shui, HL; Luo, RS or concate me.. Recommanded Product: 105-13-5

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COA of Formula: C8H10O2. In 2021 J CHEM TECHNOL BIOT published article about AROMATIC ALCOHOLS; MULTICOMPONENT SYNTHESIS; TIO2 NANOPARTICLES; AEROBIC OXIDATION; TITANIUM-DIOXIDE; IONIC LIQUIDS; METAL-OXIDES; EFFICIENT; ALDEHYDES; DEGRADATION in [Taghavi, Shaghayegh; Amoozadeh, Ali; Nemati, Firouzeh] Semnan Univ, Fac Chem, Dept Organ Chem, Semnan 3513119111, Iran in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

BACKGROUND Deep eutectic solvents (DESs) are prepared by mixing solid organic precursors to form a liquid driven from strong hydrogen-bond interactions. The physical and chemical properties of these compounds have been widely investigated, and it has been shown that they are benign media for biotransformations, organicsynthesis, biodieselpreparation, and a sustainable media for nanoscale and functional materials. RESULTS This study is the first report on the synthesis of n-TiO2-P25@TDI@DES (urea: ZnCl2) with photo catalytic activity. This nano photocatalyst was obtained through covalent grafting of TiO2-P25 nanoparticles to an inexpensive and highly reactive linker (2,4-toluene diisocyanate). The presented nano photocatalyst has been employed as a covalently grafted Lewis acidic deep eutectic solvent to oxidize various primary benzyl alcohols to their corresponding carbonyl compounds by sodium nitrate as oxidant, under visible light exposure. CONCLUSION This highly efficient nanocatalyst was investigated by various characterization techniques including fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM with EDX), and elemental analysis. Owing to its enhanced catalytic activity, thermal stability, and environmentally friendly nature, the present method can be regarded as an attractive green chemistry approach. (c) 2020 Society of Chemical Industry (SCI)

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Taghavi, S; Amoozadeh, A; Nemati, F or concate me.. COA of Formula: C8H10O2

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