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Chahboun, R; Botubol-Ares, JM; Duran-Pena, MJ; Jimenez, F; Alvarez-Manzaneda, R; Alvarez-Manzaneda, E in [Botubol-Ares, Jose Manuel; Jesus Duran-Pena, Maria] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Campus Univ Rio San Pedro S-N,4a Planta, Cadiz 11510, Spain; [Chahboun, Rachid; Jimenez, Fermin; Alvarez-Manzaneda, Enrique] Univ Granada, Fac Ciencias, Inst Biotecnol, Dept Quim Organ, Granada 18071, Spain; [Alvarez-Manzaneda, Ramon] Univ Almeria, Dept Quim & Fis, Area Quim Organ, Almeria 04120, Spain published Deconjugative alpha-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids in 2021, Cited 37. Recommanded Product: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A general and efficient method for the deconjugative alpha-alkylation of alpha,beta-unsaturated aldehydes promoted by a synergistic effect between (BuOK)-Bu-t and NaH, which considerably increases the reaction rate under mild conditions, is reported. The beta,gamma-unsaturated aldehyde, resulting from the alpha-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids.

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Reference:
Alcohol – Wikipedia,
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