Category: alcohols-buliding-blocks. Midya, SP; Subaramanian, M; Babu, R; Yadav, V; Balaraman, E in [Midya, Siba P.; Subaramanian, Murugan; Babu, Reshma; Balaraman, Ekambaram] Indian Inst Sci Educ & Res IISER Tirupati, Dept Chem, Tirupati 517507, Andhra Pradesh, India; [Yadav, Vinita] CSIR Natl Chem Lab CSIR NCL, Organ Chem Div, Pune 411008, Maharashtra, India published Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.
The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.
Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Midya, SP; Subaramanian, M; Babu, R; Yadav, V; Balaraman, E or concate me.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts