Category: alcohols-buliding-blocks. I found the field of Chemistry very interesting. Saw the article The Detosylation of Chiral 1,2-Bis(tosylamides) published in 2021, Reprint Addresses Keller, PA (corresponding author), Univ Wollongong, Sch Chem & Mol Biosci, Mol Horizons, Wollongong, NSW 2522, Australia.; Keller, PA (corresponding author), Illawarra Hlth & Med Res Inst, Wollongong, NSW 2522, Australia.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.
The deprotection of chiral 1,2-bis(tosylamides) to their corresponding 1,2-diamines is mostly unsuccessful under standard conditions. In a new methodology, the use of Mg/MeOH with sufficient steric additions allows the facile synthesis of 1,2-diamines in 78-98% yields. These results are rationalized using density functional theory and the examination of inner and outer-sphere reduction mechanisms.
Category: alcohols-buliding-blocks. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Gaston, JJ; Tague, AJ; Smyth, JE; Butler, NM; Willis, AC; Hommes, NV; Yu, HB; Clark, T; Keller, PA or concate me.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts