Adding a certain compound to certain chemical reactions, such as: 111-45-5, 2-(Allyloxy)ethanol, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound, Product Details of 111-45-5, blongs to alcohols-buliding-blocks compound. Product Details of 111-45-5
Reactions under ambient pressure: In a glove box, a 4 ml_ vial equipped with a magnetic stirring bar and a screw cap was charged with the substrate (0.1 mmol) and 2 mg of hexamethylbenzene (internal standard). Then a solution of the catalyst (5×10″3 mmol, 5 mol %) dissolved in the right amount of toluene to achieve the final concentration of 1 M in substrate, was added to the vial containing the substrate and the internal standard. The vial was closed and the reaction mixture was stirred at room temperature (22 SC). Samples (about 10 mu_) of the reaction mixture were withdrawn at regular time intervals, and quenched with an excess of ethyl vinyl ether. Determination of conversions, yields, and Z-selectivities were carried out by comparing the integrals of the peaks due to the olefinic protons of substrates and products, identified by comparison with literature data,( 20, 37-41 ) with that of the internal standard.
At the same time, in my other blogs, there are other synthetic methods of this type of compound,111-45-5, 2-(Allyloxy)ethanol, and friends who are interested can also refer to it.
Reference:
Patent; BERGEN TEKNOLOGIOVERFØRING AS; JENSEN, Vidar Remi; OCCHIPINTI, Giovanni; (64 pag.)WO2017/9232; (2017); A1;,
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