Application of 27646-80-6, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 27646-80-6, Name is 2-Methyl-2-(methylamino)propan-1-ol, SMILES is CC(NC)(C)CO, belongs to alcohols-buliding-blocks compound. In a article, author is Liao, Kui, introduce new discover of the category.
Highly Enantioselective CuAAC of Functional Tertiary Alcohols Featuring an Ethynyl Group and Their Kinetic Resolution
The first highly enantioselective Cu-I-catalyzed azide-alkyne cycloaddition (CuAAC) of tertiary alcohols and their kinetic resolution is reported. This approach allows facile access to multifunctional tertiary alcohols featuring an alpha-ethynyl or alpha-triazole moiety, and represents the first successful kinetic resolution of racemates with a tetrasubstituted carbon stereocenter via CuAAC. Newly developed pyridinebisoxazoline (PYBOX) ligands with a C4 phosphonate group play a key role.
Application of 27646-80-6, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 27646-80-6 is helpful to your research.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts